A Stable Polyoxometalate-based Coordination Polymer for Light Driven Degradation of Organic Dye Pollutant  

作　　者：WANG Man WU Xiao-Yuan WANG Sa-Sa LU Can-Zhong 王曼;吴小园;王洒洒;卢灿忠(College of Chemistry,Fuzhou University,Fuzhou 350108,China;CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Provincial Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;University of Chinese Academy of Sciences,Beijing 100049,China;Xiamen Institute of Rare Earth Materials,Chinese Academy of Sciences,Xiamen 361021,China)

机构地区：[1]College of Chemistry,Fuzhou University,Fuzhou 350108,China [2]CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Provincial Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China [3]University of Chinese Academy of Sciences,Beijing 100049,China [4]Xiamen Institute of Rare Earth Materials,Chinese Academy of Sciences,Xiamen 361021,China

出　　处：《Chinese Journal of Structural Chemistry》2021年第11期1449-1455,1406,共8页结构化学（英文）

基　　金：Supported by the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000);the National Natural Science Foundation of China(21521061,21773247,21875252,52073286)。

摘　　要：A new POM-based coordination polymer,[Cl_(2)Cu^(Ⅰ)_(11)(trz)_(8)][H_(3)SiW_(12)O_(40)](1),was successfully obtained under hydrothermal reaction.The compound was characterized by single-crystal X-ray diffraction,TGanalyses,IR spectra and PXRD analysis.Compound 1 shows extreme stability and outstanding catalytic activity to the degradation of organic dye pollutant.

关 键 词：polyoxometalate-based coordination polymer photocatalysis 1 2 4-TRIAZOLE 

分 类 号：X703[环境科学与工程—环境工程] O641.4[理学—物理化学] O643.36[理学—化学]