Synthesis and Characterization of Hyperbranched Epoxy with Terminal Ally Group and Its Application of Toughen Bismaleimide  

作　　者：ZHANG Ze WANG Xiang CHEN Danxia CHEN Yao MA Wei CHEN Weiping 章泽;王翔;CHEN Danxia;CHEN Yao;MA Wei;CHEN Weiping(School of Materials Science and Engineering,Wuhan University of Technology,Wuhan 430070,China)

机构地区：[1]School of Materials Science and Engineering,Wuhan University of Technology,Wuhan 430070,China

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2021年第5期720-729,共10页武汉理工大学学报（材料科学英文版）

基　　金：Funded by National Natural Science Foundation of China(No.51672201)。

摘　　要：A hyperbranched epoxy(AHEP)resin with terminal allyl groups was synthesized.The number average molecular weight of the synthesized AHEP is 1260,the multi-dispersion coefficient is 1.88,and the branching degree is 0.9.The hyperbranched epoxy resin and bismaleimide(BMI)monomer were heated to extend the chain and then blended and cured with methyl nadic anhydride.Studies have found that when the molar ratio of AHEP:BDM is 1:2,the mechanical properties and heat resistance of the resin casting body reach the best.Among them,the impact toughness was 15.05 kg/m^(2),the bending strength was 101 MPa,and the heat resistance temperature index was 229.23℃.We used AHEP to toughen bismaleimide resin in three ways simultaneously:hyperbranched structure,allyl copolymerized brackets chain and flexible side chain(epoxy group)addition.Experiments have proved that AHEP can improve the flexibility of the BMI chain and maintain its heat resistance,thereby forming a matrix with excellent mechanical properties and processing properties.

关 键 词：HYPERBRANCHED toughen RESINS 

分 类 号：TQ323[化学工程—合成树脂塑料工业]