席夫碱钼配合物在硫醚氧化中的应用进展  

Appliacation progress of Schiff base molybdenum complexes in thioether oxidation

作　　者：任艳君 杨兰 胡俊悦 段宗岳 王伟立 Ren Yanjun;Yang Lan;Hu Junyue;Duan Zongyue;Wang Weili(School of Chemistry and Materials Science,Ludong University,Yantai 264025,China;High School of Yantai Development Zone,Yantai 264000,China)

机构地区：[1]鲁东大学化学与材料科学学院,山东烟台264025 [2]烟台开发区高级中学,山东烟台264000

出　　处：《化学推进剂与高分子材料》2021年第6期14-18,共5页Chemical Propellants & Polymeric Materials

基　　金：国家自然科学基金(21901098);山东省自然科学基金(ZR2017PB006);鲁东大学引进人才启动基金(LB2017003)。

摘　　要：介绍了均相及非均相席夫碱钼配合物催化剂的开发,以及席夫碱钼配合物催化氧化硫醚制备亚砜、砜中的重要金属催化体系和一些异相催化体系的研究现状,指出硫醚直接氧化是制备亚砜和砜的主要方法之一,在众多关于硫醚选择性氧化反应的研究中,过氧化氢作为清洁氧化剂备受关注。The development of the homogeneous and heterogeneous Schiff base molybdenum complex catalysts as well as the research status of the important metal catalytic systems and some heterogeneous catalytic systems used in the preparation of sulfoxides and sulfones by catalytically oxidizing thioether with the Schiff base molybdenum complexes are introduced.It is pointed out that the direct oxidation of thioether is one of the main methods to prepare sulfoxides and sulfones.Among many studies on the selective oxidation reaction of thioether,hydrogen peroxide has attracted much attention as a clean oxidant.

关 键 词：席夫碱 钼 硫醚 催化 氧化 

分 类 号：Q641.4[生物学—生物物理学]