Amorphous iron-nickel phosphide nanocone arrays as efficient bifunctional electrodes for overall water splitting  

作　　者：Guang Liu Yun Wu Rui Yao Fei Zhao Qiang Zhao Jinping Li 

机构地区：[1]Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization,College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan,Shanxi 030024,China [2]Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education),College of Chemistry,Nankai University,Tianjin 300071,China

出　　处：《Green Energy & Environment》2021年第4期496-505,共10页绿色能源与环境（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.21878204);Key R&D program of Shanxi Province(International Cooperation,201903D421073)。

摘　　要：The synthesis of low-cost and highly active electrodes for both oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)is very important for water splitting.In this work,the novel amorphous iron-nickel phosphide(FeP-Ni)nanocone arrays as efficient bifunctional electrodes for overall water splitting have been in-situ assembled on conductive three-dimensional(3D)Ni foam via a facile and mild liquid deposition process.It is found that the FeP-Ni electrode demonstrates highly efficient electrocatalytic performance toward overall water splitting.In 1 M KOH electrolyte,the optimal FeP-Ni electrode drives a current density of 10 mA cm^(-2) at overpotential of 218 mV for the OER and120 mV for the HER,and can attain such current density for 25 h without performance regression.Moreover,a two-electrode electrolyzer comprising the FeP-Ni electrodes can afford 10 mA cm^(-2) electrolysis current at a low cell voltage of 1.62 V and maintain long-term stability,as well as superior to that of the coupled RuO_(2)/NFk Pt/C/NF cell.Detailed characterizations confirm that the excellent electrocatalytic performances for water splitting are attributed to the unique 3D morphology of nanocone arrays,which could expose more surface active sites,facilitate electrolyte diffusion,and benefit charge transfer and also favorable bubble detachment behavior.Our work presents a facile and cost-effective pathway to design and develop active self-supported electrodes with novel 3D morphology for water electrolysis.

关 键 词：Water splitting Oxygen evolution reaction Hydrogen evolution reaction PHOSPHIDES Bifunctional electrodes 

分 类 号：TQ116.2[化学工程—无机化工] TQ426