新型蓝光酰腙化合物的合成、表征及光学性质研究  

Study on Synthesis,Characterization and Optical Properties of Novel Blue Light Acylhydrazones

作　　者：王爱民 凌大新 范颖异 李丹 张杰 Wang Aimin;Ling Daxin;Fan Yingyi;Li Dan;Zhang Jie(Yeshili New Materials Co.,Ltd.,Zhejiang,318000;Department of Chemistry,School of Pharmaceutical and Materials Engineering,Taizhou University,Zhejiang,318000)

机构地区：[1]夜视丽新材料股份有限公司,浙江318000 [2]台州学院医药化工与材料工程学院,浙江318000

出　　处：《当代化工研究》2021年第22期30-32,共3页Modern Chemical Research

基　　金：浙江省自然科学基金(LY21B010001);国家自然科学基金(21501128);台州市工业类科技计划项目(21gyb18)。

摘　　要：将2-吡咯甲酸甲酯和水合联氨反应合成了中间产物2-吡咯甲酰肼,随后2-吡咯甲酰肼和各种醛缩合后合成了一系列新型酰腙化合物。对合成的酰腙化合物通过核磁共振、红外等方法进行了结构表征。另外,使用紫外、荧光等方法对上述化合物进行了吸收和发光性质的测试。2-pyrroloyl hydrazide was synthesized from methyl 2-pyrrolate and hydrazine hydrate,and then a series of hydrazones were synthesized by condensation of 2-pyrroloyl hydrazide with various aldehydes.The synthesized hydrazones were characterized by ^(1)H NMR and IR.In addition,UV and fluorescence methods were used to study the absorption and luminescent properties of these compounds.

关 键 词：酰腙 合成 表征 发光性质 

分 类 号：O621.2[理学—有机化学]