基于碳化钽涂层改性碳基材料的研究进展  

Research progress on tantalum carbide coatings on carbon materials

作　　者：刘兴亮 戴煜[1,2,3,4] 王卓健 吴建 LIU Xing-liang;DAI Yu;WANG Zhuo-jian;WU Jian(School of Materials Science and Engineering,Nanchang University,Nanchang 330031,China;International Institute of Materials Innovation,Nanchang University,Nanchang 330031,China;Advanced Corporation for Materials&Equipments Co.,Ltd.,Changsha 410118,China;Hunan Zhongke Dingli Technology Innovation Research Institute Co.,Ltd.,Changsha 410118,China)

机构地区：[1]南昌大学,材料科学与工程学院,江西南昌330031 [2]南昌大学,国际材料创新研究院,江西南昌330031 [3]湖南顶立科技有限公司,湖南长沙410118 [4]湖南中科顶立技术创新研究院有限公司,湖南长沙410118

出　　处：《新型炭材料》2021年第6期1049-1061,共13页New Carbon Materials

基　　金：江西省青年基金项目(20192BAB216009);湖南省科技计划项目(2019WK2051);长沙市科技计划项目(kh2003023).

摘　　要：石墨、炭纤维、炭/炭复合材料等碳基材料广泛应用在航空航天、能源汽车、化工等领域,但炭材料在高温有氧环境下易氧化和不耐氨气、耐划性能较差等缺点,难以满足人们对炭材料越来越苛刻的使用要求,严重制约其发展和实际应用。碳化钽(TaC)具有优异的高温力学稳定性及高温耐腐蚀、耐烧蚀等优点,并与炭材料具有良好的化学相容性和力学相容性,能够对炭材料有效保护,引起国内外研究人员对TaC涂层改性碳基材料的广泛研究。本文系统介绍了在石墨、炭纤维、炭/炭复合材料3种碳基材料表面制备TaC涂层的研究进展,阐述了化学气相沉积工艺(如气体流量、沉积温度、沉积压力)对TaC涂层改性碳基材料的影响规律,讨论了TaC涂层的发展趋势及展望了发展方向。Carbon materials,such as graphite,carbon fibers and C/C composites,have a high specific modulus and specific strength,especially at high temperatures.However,they corrode easily in air or ammonia at high temperatures and have poor scratching resistance.Tantalum carbide(TaC)has an excellent high-temperature mechanical stability,high-temperature corrosion resistance,high-temperature ablation resistance and good chemical and mechanical compatibility with carbon materials.This paper summarizes research progress on coating TaC on graphite,carbon fibers and C/C composites.The coating methods and their effects on the properties of carbon materials are introduced,including plasma spraying,chemical vapor deposition,chemical vapor infiltration,slurry coating,sol coating and reactive coating in molten salt media with a focus on chemical vapor deposition.Development trends and research directions on the subject of TaC coating are discussed.

关 键 词：石墨 炭纤维 炭/炭复合材料 TAC涂层 化学气相沉积 

分 类 号：TB33[一般工业技术—材料科学与工程]