氯添加对燃煤过程中汞析出规律的影响  

Effect of chlorine addition on mercury precipitation during coal combustion

作　　者：肖国振 仲兆平[1] 姜超 韩磊 马天霆 张杉 金保昇[1] XIAO Guozhen;ZHONG Zhaoping;JIANG Chao;HAN Lei;MA Tianting;ZHANG Shan;JIN Baosheng(School of Energy and Environment,Southeast University,Nanjing 210096,Jiangsu,China;National Energy Taicang Power Generation Limited Company,Suzhou 215400,Jiangsu,China)

机构地区：[1]东南大学能源与环境学院,江苏南京210096 [2]国能太仓发电有限公司,江苏苏州215400

出　　处：《化工进展》2021年第12期6557-6563,共7页Chemical Industry and Engineering Progress

基　　金：国能集团国华电力公司科技创新项目(2019054)。

摘　　要：首先利用管式炉对燃煤及燃煤加氯后煤中汞排放进行研究,结果表明,对于神混煤而言,原煤燃烧后烟气中单质Hg^(0)和氧化态汞Hg^(2+)的比例分别为74.3%、25.7%。添加Cl后,烟气中Hg^(2+)的比例有所上升,当加氯量为0.015%、0.030%和0.045%时,烟气中Hg^(2+)的比例分别上升为32.7%、36.1%和40%,随加氯量的增加,其对汞的氧化作用也随之增强。在现场工程示范试验中,利用脱硫废水中的氯氧化烟气中的汞,以达到脱硫废水与烟气中的汞协同脱除的目的。结果表明,随着脱硫废水喷洒煤的量越大,进入SCR烟气中Hg^(2+)比例增大,经过SCR后Hg^(2+)的比例随之增大。由于飞灰对Hg^(2+)的吸附能力较Hg^(0)强,电除尘系统的脱汞效率提高,但脱硫废水喷洒煤对湿电除尘系统的脱汞效率影响不大。总之,脱硫废水喷洒量越大,燃煤机组烟气净化设备对汞协同去除效率也随之提高。In this paper,mercury emissions from coal combustion and coal chlorination were investigated by using a tubular furnace.The results showed that the percentage of simple substance Hg^(0) and oxidized Hg^(2+) in the flue gas after the combustion of raw coal is 74.3%and 25.7%,respectively.With the addition of Cl,the proportion of Hg^(2+) in the flue gas increased.When the chlorine was 0.015%,0.030%and 0.045%,the ratio of Hg^(2+) in the flue gas increased by 32.7%,36.1%and 40%,respectively,with the increase of chlorine,and its oxidation of mercury was also enhanced.In the field engineering demonstration test,mercury in the hydraulitis in the desulfurized wastewater was utilized to achieve the purpose of desulfurization wastewater and the mercury in the flue gas.With the increase of the amount of desulfurization wastewater sprayed on coal,the proportion of Hg^(2+) in the flue gas entering the SCR and passing through the SCR increased.Since the adsorption capacity of fly ash to Hg^(2+) was higher than that of Hg^(0),the mercury removal efficiency of the electrostatic precipitation system was improved.However,desulfurization wastewater spray coal on the demellular efficiency of wet electric dust removal system was not affected.Conclusively,with increase in the amount of the desulfurization wastewater spray,removal efficiency of mercury by flue gas purification equipment of coal-fired units could be raised.

关 键 词：烟气脱汞 管式炉 氯添加 脱硫废水 

分 类 号：TQ534.9[化学工程—煤化学工程]