连续RAFT光聚合法合成聚羧酸减水剂  

Preparation of Polycarboxylate-Based Superplasticizer by Continuous Photo-Mediated RAFT Polymerization

作　　者：彭荩影 钱珊珊 姚燕 王子明[2] 郑春扬[1] PENG Jinying;QIAN Shanshan;YAO Yan;WANG Ziming;ZHENG Chunyang(Jiangsu Province Engineering Research Center(ARIT)of Concrete Polymer Additives,Jiangsu China Railway ARIT New Materials Co.,Ltd.,Nanjing 211505,China;College of Materials Science and Engineering,Beijing University of Technology,Beijing 100124,China;Sate Key Laboratory of Green Building Materials,China Building Materials Academy,Beijing 100124,China)

机构地区：[1]江苏奥莱特新材料股份有限公司江苏省(奥莱特)混凝土高分子助剂工程技术研究中心,江苏南京211505 [2]北京工业大学材料科学与工程学院,北京100124 [3]中国建筑材料科学研究总院绿色建筑材料国家重点实验室,北京100124

出　　处：《建筑材料学报》2021年第6期1328-1334,共7页Journal of Building Materials

基　　金：国家自然科学基金资助项目(51578025);北京市属高校高水平教师队伍建设支持计划青年拔尖人才培育计划项目(CIT&TCD201804008)。

摘　　要：以甲基丙烯酸聚乙二醇单甲醚酯和丙烯酸为主要原料,通过光调控水相可逆加成-断裂链转移(RAFT)聚合,在连续管式反应器中成功合成了聚羧酸减水剂,并采用核磁共振仪(NMR)、傅里叶红外光谱仪(FTIR)、凝胶渗透色谱仪(GPC)和动态光散射仪(DLS)等表征了减水剂的结构.结果表明:RAFT聚合聚羧酸减水剂的相对分子质量分布更集中,分散性和分散保持性更好;连续RAFT聚合工艺可以实现可控聚合物的连续化生产,连续管式反应器中有限的氧含量使得RAFT聚合可以在不预先除氧的情况下成功进行,为聚羧酸减水剂的可控合成提供了新的思路.A kind of polycarboxylate⁃based superplasticizer(PCE)was successfully synthesized by photo⁃mediated reversible addition⁃fragmentation chain transfer(RAFT)polymerization with poly(ethylene glycol)methyl ether methacrylate(PEGMA)and acrylic acid(AA)as the main material.The molecular structure of the products was characterized by nuclear magnetic resonance(NMR),gel permeation chromatography(GPC),infra⁃red spectrum(IR)and dynamic light scattering(DLS).The results show that the product has narrow distribution of the relative molecular mass,the advantages of strong disperse ability and excellent slump retention.Moreover,continuous RAFT process can realize continuous production of controlled polymers.The limited oxygen content in the continuous tubular reactor allows RAFT polymerization to be successfully carried out without prior deoxygenation process,which can provide a new idea for controlled synthesis of polycarboxylate⁃based superplasticizer.

关 键 词：连续管式反应器 光调控 可逆加成-断裂链转移聚合 聚羧酸减水剂 

分 类 号：TU528.042.2[建筑科学—建筑技术科学]