Colorimetric recognition of melamine in milk using novel pincer zinc complex stabilized gold nanoparticles  

作　　者：Xiaoling Bao Jianhong Liu Qingshu Zheng Lixin Duan Yuzhu Zhang Junlong Qian Tao Tu 

机构地区：[1]Institute of Quality Inspection of Food and Cosmetics,Shanghai Institute of Quality Inspection and Technical Research,Shanghai 200233,China [2]Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials,Department of Chemistry,Fudan University,Shanghai 200438,China [3]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200232,China [4]College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450001,China

出　　处：《Chinese Chemical Letters》2021年第10期3023-3026,共4页中国化学快报（英文版）

基　　金：Financial support from the State General Administration of the People’s Republic of China for Quality Supervision and Inspection and Quarantine(No.2016QK122);the Science and Technology Projects of Jiangxi Province(No.20181BBH80007);Shanghai Institute of Quality Inspection and Technical Research;the Department of Chemistry,Fudan University。

摘　　要：A convenient colorimetric approach for visual detection of melamine in raw milk was realized by using gold nanoparticles(AuNPs)stabilized by an unsymmetrical terpyridyl zinc complex with a thymine fragment at one terminal and a quaternary ammonium salt at the other.Even without pre-addition of melamine or relative additives,obvious color change from red to blue was observed by naked eye in the presence of trace amount of melamine,which was attributed to the alternation of aggregation state of AuNPs caused by the selective binding between the thymine fragment and melamine via triple hydrogenbonding interactions.Remarkably,the detection limit for melamine was as low as 2.4 ppb,providing a highly sensitive and efficient approach for the visual detection of melamine.

关 键 词：Colorimetric recognition Gold nanoparticles Hydrogen-bonding interactions Pincer zinc complex MELAMINE 

分 类 号：TS252.7[轻工技术与工程—农产品加工及贮藏工程] O657.3[轻工技术与工程—食品科学与工程]