Decatungstate as a direct hydrogen atom transfer photocatalyst for synthesis of trifluromethylthioesters from aldehydes  

作　　者：Xiaochen Wang Jianyang Dong Yuxiu Liu Hongjian Song Qingmin Wang 

机构地区：[1]State Key Laboratory of Elemento-Organic Chemistry,Research Institute of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China [2]Collaborative Innovation Center of Chemical Science and Engineering(Tianjin),Tianjin 300071,China

出　　处：《Chinese Chemical Letters》2021年第10期3027-3030,共4页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China (Nos.21732002, 22077071) for generous financial support for our programs。

摘　　要：We have developed a versatile,mild protocol for trifluoromethylthiolation reactions of aldehydes with catalysis by a decatungstate hydrogen atom transfer photocatalyst under redox-neutral conditions.The protocol is highly selective,operationally simple,and compatible with a wide array of sensitive functional groups.It can be used for late-stage functionalization of bioactive molecules,which makes it convenient for drug discovery.

关 键 词：ALDEHYDES Decatungstate photocatalyst Redox-neutral Hydrogen atom transfer Trifluoromethylthiolation 

分 类 号：TQ225.27[化学工程—有机化工] O643.36[理学—物理化学] O644.1[理学—化学]