基于燃烧机理对克劳斯工艺燃烧参数的优化  

Optimization of combustion parameters of Claus process based on combustion mechanism

作　　者：田芳勇 黄山 朱军 周屈兰[2] 张杰 刘师承 古小红 尹琦岭 TIAN Fang-yong;HUANG Shan;ZHU Jun;ZHOU Qu-lan;ZHANG Jie;LIU Shi-cheng;GU Xiao-hong;YIN Qi-ling(Petroleum Engineering Technology Research Institute,Zhongyuan Oilfield Company,SINOPEC,Puyang 457000,Henan,China;State Key Laboratory of Multiphase Flow in Power Engineering,Xi’an Jiaotong University,Xi’an 710049,Shannxi,China;Puguang Branch of Zhongyuan Oilfield Company,SINOPEC,Dazhou 636158,Sichuan,China)

机构地区：[1]中国石油化工股份有限公司中原油田分公司石油工程技术研究院,河南濮阳457000 [2]西安交通大学动力工程多相流国家重点实验室,陕西西安710049 [3]中国石油化工股份有限公司中原油田普光分公司,四川达州636158

出　　处：《天然气化工—C1化学与化工》2021年第6期109-115,共7页Natural Gas Chemical Industry

基　　金：国家科技重大专项(2016ZX05017-006-HZ02)。

摘　　要：含H2S气田开采量占我国天然气开采量的60%,大型气田一般采用克劳斯硫磺回收工艺处理天然气中分离出来的酸性气。结合以往研究,通过分析简化,建立了完整的H_(2)S燃烧机理与克劳斯工艺流程模拟模块,进一步将模拟结果与某气田实际运行参数进行了对比,并对实炉运行参数进行了优化。研究发现,当过量空气系数为0.93、焚烧炉温为1273 K、冷却水温为500 K时,硫磺回收率可达到最优。将该优化结果应用于实炉,硫磺回收率达到97.54%,比原始工况提升了1.5%。The production of gas fields containing H_(2)S accounts for 60%of China's natural gas production,Claus sulfur recovery process is generally used to treat acidic gas separated from natural gas in large gas fields.Combined with previous studies,through analysis and simplification,a complete H_(2)S combustion mechanism and a Claus process simulation module were established.The simulation results were further compared with actual operation parameters of a gas field,and the actual operation parameters were optimized.The results show that when the excess air coefficient is 0.93,the incineration temperature is 1273 K and the cooling water temperature is 500 K,the sulfur recovery rate can reach the best.Applying the optimization results to the actual production,the sulfur recovery rate reaches 97.54%,that is 1.5%higher than the original condition.

关 键 词：克劳斯工艺 燃烧反应机理 燃烧参数 流程模拟 

分 类 号：TQ038[化学工程] X701.3[环境科学与工程—环境工程]