有机粘土/丁基橡胶纳米复合材料的结构与性能  

Structure and Properties of Organic Clay/IIR Nanocomposites

作　　者：王江乐 梁玉蓉 任绒艇 刘兵兵 孙琪 WANG Jiangle;LIANG Yurong;REN Rongting;LIU Bingbing;SUN Qi(Taiyuan Institute of Technology,Taiyuan 030008,China)

机构地区：[1]太原工业学院材料工程系,山西太原030008

出　　处：《橡胶工业》2021年第12期912-916,共5页China Rubber Industry

基　　金：国家自然科学基金资助项目(51573124)。

摘　　要：采用熔体共混法制备有机粘土(OC)/丁基橡胶(IIR)纳米复合材料(IIRCNs),研究OC的结构变化以及IIRCNs的物理性能、微观相态和气体阻隔性能。结果表明:OC用量为10份时,IIRCNs中的OC片层间距增至4.09 nm(OC的起始片层间距为2.96 nm),形成插层结构良好的复合材料,IIRCNs的拉伸强度为16.20 MPa,较IIR胶料的8.00 MPa提高102%,且OC在橡胶基质中的分散形态较为细致、均匀;经过预应力循环拉伸处理后,IIRCNs的拉伸强度达到17.30MPa,较未预应力循环处理的16.20MPa提高6.8%;具有较大长径比的OC均匀分布在橡胶基质中,大幅提高复合材料的气体阻隔性能,气体渗透率较IIR胶料下降25%。Organic clay(OC)/butyl rubber(IIR) nanocomposites(IIRCNs) were prepared by melt blending method,and the structural changes of OC and the physical properties,microscopic phase state and gas barrier performances of IIRCNs were studied. The results showed that when the additional level of OC was 10 phr,the clay lamellar spacing of OC in IIRCNs increased to 4. 09 nm(the initial lamellar spacing of OC was 2. 96 nm),indicating the formation of intercalated structure. The tensile strength of IIRCNs was 16. 20 MPa,which was 102% higher than IIR compound’s 8. 0 MPa,and the dispersion of OC in the rubber matrix was finer and more uniform. After prestressed cyclic tensile treatment,the tensile strength of IIRCNs reached 17. 30 MPa,which was 6. 8% higher than that of the IIRCNs without prestressed cyclic tensile treatment. The OC with large aspect ratio was uniformly distributed in the rubber matrix,which greatly improved the gas barrier performances of the composites,and the gas permeability of IIRCNs was 25% lower than that of IIR compound.

关 键 词：丁基橡胶 有机粘土 纳米复合材料 拉伸性能 滞后圈 微观相态 气体阻隔性能 

分 类 号：TQ333.6[化学工程—橡胶工业] TQ330.383