[Ni(bpy)_(3)]_(2){[Ni(bpy)_(2)(H_(2)O)][AsW^(VI)_(10)W^(V)_(2)O_(40)]}·H_(2)O簇合物的合成与表征  

Synthesis and characterization of [Ni(bpy)_(3)]_(2){[Ni(bpy)_(2)(H_(2)O)][AsW^(VI)_(10)W^(V)_(2)O_(40)]}·H_(2)O Clusters

作　　者：张雨薇 沈鹏鹏 ZHANG Yu-wei;SHEN Peng-peng(College of Chemistry,Jilin Normal University,Siping Jilin 136000,China;Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University),Ministry of Education,Changchun Jilin 130103,China)

机构地区：[1]吉林师范大学化学学院,吉林四平136000 [2]吉林师范大学,环境友好材料制备与应用教育部重点实验室,吉林长春130103

出　　处：《辽宁化工》2021年第12期1745-1747,共3页Liaoning Chemical Industry

基　　金：国家自然科学基金项目(项目编号:21805110);吉林省教育厅项目(项目编号:JJKH20210441KJ)。

摘　　要：合成了一种带帽的Keggin型化合物[Ni(bpy)_(3)]_(2){[Ni(bpy)_(2)(H_(2)O)][AsW^(VI)_(10)W^(V)_(2)O_(40)]}·H_(2)O,该化合物属于单斜晶系,空间群C2/c,晶胞参数a=46.743(4)Å、b=14.3433(14)Å、c=26.060(3)Å、β=90.169(2)°、V=17472(3)Å^(3),簇阴离子具有Keggin构型。在结构测定的基础上,对化合物进行了红外分析。A type of Keggin type compound with cap,[Ni(bpy)_(3)]_(2){[Ni(bpy)_(2)(H_(2)O)][AsW^(VI)_(10)W^(V)_(2)O_(40)]}·H_(2)O,was synthesized.This compound belongs to monoclinic system,space group C2/c,crystal cell parameters:a=46.743(4)Å,b=14.3433(14)Å,c=26.060(3)Å,β=90.169(2)°,V=17472(3)Å^(3).The cluster anions have Keggin configuration.On the basis of structure determination,the compounds were analyzed by IR.

关 键 词：水热合成 金属氧簇 超分子 结构与性能 

分 类 号：O641.3[理学—物理化学]