Recent Progress in Metal-Organic Frameworks@Cellulose Hybrids and Their Applications  

作　　者：Xiongli Liu Yun Xiao Zhiyuan Zhang Zifeng You Jinli Li Dingxuan Ma Baiyan Li 

机构地区：[1]School of Materials Science and Engineering,National institute for Advanced Materials,TKL of Metal and Molecule-Based Material Chemistry,Nankai University,Tianjin 300350,China [2]College of Chemistry and Molecular Engineering,Laboratory of Eco-chemical Engineering,Ministry of Education,Qingdao University of Science and Technology,Qingdao 266042,China [3]General English Department,College of Foreign Languages,Nankai University,Tianjin 300071,China

出　　处：《Chinese Journal of Chemistry》2021年第12期3462-3480,共19页中国化学（英文版）

基　　金：This work was supported by NSFC(No.21978138);China and the Fundamental Research Funds for the Central Universities(Nankai University).

摘　　要：In recent years,metal-organic frameworks(MOFs)are attracting increasing attention due to their charming properties.However,the intrinsic fragility,powdered crystalline state,and poor processibility of MOFs hinder their further application.By this,the designs of MOF-based aerogels,hydrogels,membranes are effective ways to solve this problem.Graphene,silica,synthetic polymer and cellulose are the commonly used raw materials for fabricating MOF-based aerogels,hydrogels,and membranes.Among them,cellulose and its derivatives are the best candidates to support the powdered MOFs from the perspectives of economy,environmental protection and property.This review focuses on discussing the advantages of MOF@cellulose hybrids in applications such as water treatment,antibacterial,gas separation and adsorption,energy storage,drug delivery,catalysis,and other smart composites.MOF@cellulose-based aerogels,hydrogels and membranes can provide valuable guidance for investigating the practical application of MOFs in terms of processability,reusability,stability and easiness in handling.

关 键 词：Metal-organic frameworks CELLULOSE Membranes Organic-inorganic hybrid composites APPLICATION 

分 类 号：O64[理学—物理化学]