光电化学阴极保护技术研究进展  

Research progress in photochemical cathodic protection tech-nology

作　　者：蒋继宏 张小影 金祖权[1] JIANG Ji-hong;ZHANG Xiao-ying;JIN Zu-quan(School of Civil Engineering,Qingdao University of Technology,Qingdao 266033,China)

机构地区：[1]青岛理工大学土木工程学院,山东青岛266033

出　　处：《海洋科学》2021年第12期150-161,共12页Marine Sciences

基　　金：国家自然科学基金项目(U1806225,41976044,51609233)。

摘　　要：海洋环境下的金属面临着非常严峻的腐蚀问题,必须采取措施进行防护。光电化学阴极保护是一种绿色环保的新型防腐蚀技术,受到了广泛的关注。本文简要阐述了光电化学阴极保护技术的原理以及对光阳极的要求;详细介绍了以二氧化钛为代表的几种常见光阳极材料及其不同改性方法;此外还介绍了兼具储能与阴极保护功能的光阳极,它有望实现暗态下连续保护的目标;最后讨论了光电化学阴极保护技术的发展趋势。Metals in the marine environment encounter serious corrosion problems;thus,measures must be taken to protect them.Photochemical cathodic protection is a new green and environmental anti-corrosion technology,which has attracted considerable attention.This study briefly describes the principle of photochemical cathodic protection technology and the requirements for photoanode.Several common photoanode materials represented by TiO2 and their different modification methods are introduced in detail.In addition,the photoanode with the functions of energy stor-age and cathodic protection,which is expected to achieve the goal of continuous protection in the unilluminated state,is introduced.Finally,the development trend of photoelectrochemical cathodic protection technology is discussed.

关 键 词：海洋环境 腐蚀防护 光电化学阴极保护 光电半导体 二氧化钛 

分 类 号：TG174.41[金属学及工艺—金属表面处理]