N-羟基邻苯二甲酰亚胺酯在光催化烷基化反应中的研究进展  

Advances of N-Hydroxyphthalimide Esters in Photocatalytic Alkylation Reactions

作　　者：贺帅旗 李昊聪 陈晓岚[1] Igor B.Krylov Alexander O.Terent'ev 屈凌波[1] 於兵 Shuaiqi He;Haocong Li;Xiaolan Chen;Igor B.Krylov;Alexander O.Terent'evb;Lingbo Qu;Bing Yu(Green Catalysis Center,College of Chemistry,Zhengzhou University,Zhengzhou 450001,China;Zelinsky Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,119991,Russian Federation)

机构地区：[1]郑州大学化学学院绿色催化中心,郑州450001 [2]俄罗斯科学院泽林斯基有机化学研究所,俄罗斯莫斯科119991

出　　处：《有机化学》2021年第12期4661-4689,共29页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(21971224);国家自然科学基金(22071222);高等学校学科创新引智计划(111项目);高等学校学科创新引智计划(D20003);河南省高校重点科研(20A150006);河南省高校重点科研(21A150053);河南省自然科学基金(202300410375)。

摘　　要：N-羟基邻苯二甲酰亚胺(NHP)酯可以由对应的羧酸衍生而来,是一类价廉、易得、稳定、具有高光活性的化合物.近年来,NHP酯类化合物在光催化脱羧反应中受到了广泛关注.根据光催化剂的类型,综述了可见光促进下NHP酯参与的烷基化反应的研究进展.N-Hydroxyphthalimide(NHP) esters are easily available, stable, inexpensive, and highly photoactive compounds,which are derived from the corresponding carboxylic acids. In recent years, the application of NHP esters in photocatalytic decarboxylative reactions has captured huge attention. Herein, the vigorous development of photocatalytic alkylation reactions using alkyl NHP esters as alkylating reagents is summarized based on the classification of photocatalysts.

关 键 词：邻苯二甲酰亚胺酯 光催化 脱羧 烷基化 光催化剂 

分 类 号：O621.251[理学—有机化学]