可见光介导无金属的苯乙酸衍生物脱羧氘代  

Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid

作　　者：何宇航 杨慧 高冬旭 马嘉慧 邵亚敏 安光辉 李光明 Yuhang He;Hui Yang;Dongxu Gao;Jiahui Ma;Yamin Shao;Guanghui An;Guangming Li(Key Laboratory of Functional Inorganic Material Chemistry,School of Chemistry and Materials Science,Heilongjiang University,Harbin 150080)

机构地区：[1]黑龙江大学化学化工与材料学院功能无机材料化学重点实验室,哈尔滨150080

出　　处：《有机化学》2021年第12期4725-4731,共7页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21502046)资助项目.

摘　　要：报道了无金属可见光诱导的苯乙酸衍生物脱羧.在无添加剂条件下,使用廉价的氘源成功地实现了酸的直接脱羧单氘化.此外,在空气存在时,类似的催化体系能够通过脱羧氧化生成酮.A metal-free visible light-induced decarboxylation of phenylacetic acid derivatives has been successfully developed. Without the additives, direct decarboxylative monodeuteration of acids was successfully achieved using cheap deuterium sources. Besides, in presence of air, similar catalytic systems provided ketone products.

关 键 词：光化学 无金属 脱羧 氘代 

分 类 号：O621.25[理学—有机化学]