MOFs在不饱和醛选择加氢中的应用研究进展  

Progresses in the Application of MOFs in Selective Hydrogenation of Unsaturated Aldehydes

作　　者：申海玉 赵华华[1] 杨建[1] 赵军[1] 闫亮[1] 宋焕玲[1] 丑凌军[1,3] SHEN Hai-yu;ZHAO Hua-hua;YANG Jian;ZHAO Jun;YAN Liang;SONG Huan-ling;CHOU Ling-jun(State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;University of Chinese Academy of Sciences,Beijing 100049,China;Suzhou Research Institute of LICP,Chinese Academy of Sciences,Suzhou 215123,China)

机构地区：[1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000 [2]中国科学院大学,北京100049 [3]中国科学院兰州化学物理研究所苏州研究院,江苏苏州215123

出　　处：《分子催化》2021年第6期571-582,I0004,共13页Journal of Molecular Catalysis(China)

基　　金：国家自然科学基金(21773272)。

摘　　要：不饱和醛多相催化选择加氢制备不饱和醇常常被选作C=O键选择性加氢的代表性反应,长期以来一直备受关注,然而如何获得兼具高活性及高选择性的催化剂依然具有很大挑战.近年来,由于金属有机骨架(Metalorganic frameworks MOFs)材料具有的独特性能,应用在加氢领域的研究越来越多,常用做催化剂载体或直接作为催化剂,以提高不饱和醇的收率.因此,我们综述了不同MOFs及其衍生物在不饱和醛选择性加氢应用中的最新进展和技术挑战,并对这些材料的性能进行了讨论,试图通过催化剂结构、催化剂性能、反应机理等分析,为进一步合理设计有效的催化剂,实现更高的不饱和醇收率提供研究思路.It has been attracting attention for a long time that selective hydrogenation of unsaturated aldehydes to unsaturated alcohol is often selected as a representative reaction for the selective hydrogenation of C=O bond.However,it is still a great challenge to obtain the efficient catalysts with high activity and selectivity.In recent years,due to the unique properties of metal organic frameworks(MOFs)materials,they were focused on the field of hydrogenation by more and more researchers,which were often used as catalyst supports or directly as catalysts to improve the yields of unsaturated alcohols.Therefore,this paper reviews the latest progress and technical challenges of different MOFs and their derivatives in the selective hydrogenation of unsaturated aldehydes,and the properties of these materials are also discussed.In addition,the analysis of catalyst structure,catalytic performance and reaction mechanism was reviewed to provide research ideas for designing effective catalysts and achieving higher yields of unsaturated alcohols.

关 键 词：不饱和醛 选择性加氢 不饱和醇 MOFS 

分 类 号：O643.32[理学—物理化学]