Monolithic membrane reactors based on supported ionic liquid phase(SILP)materials–hydroformylation and water-gas shift case studies  

作　　者：Markus Schorner Patrick Wolf Marco Haumann 

机构地区：[1]Friedrich-Alexander-Universitaat Erlangen-Nürnberg(FAU),Lehrstuhl für Chemische Reaktionstechnik(CRT),Egerlandstr.3,91058,Erlangen,Germany [2]Forschungszentrum Jülich GmbH,Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy(IEK 11),Cauerstr.1,91058,Erlangen,Germany

出　　处：《Green Chemical Engineering》2021年第4期339-341,共3页绿色化学工程（英文）

基　　金：support from the European Commission within the H2020 projects ROMEO(grant agreement number 680395);MACBETH(grant agreement number 869896).

摘　　要：Homogeneous catalysts,usually being active in liquid environment,offer several benefits for highly selective processes.However,the often tedious product separation and catalyst recycling,requiring energy and chemical input,renders such processes energy inefficient.Here,process intensification can help to achieve a significant reduction in energy consumption and CO_(2) emissions.In this context,monolithic membrane reactors combining homogeneous catalysis with in-situ product removal are highly attractive.In order to maintain the homogeneous catalyst inside the monolithic structure,the so-called supported ionic liquid phase(SILP)technique is used.In such SILP systems,the active catalyst is dissolved in an ionic liquid,which is dispersed as thin film over the large internal surface of a porous support[1].

关 键 词：IONIC CATALYST LIQUID 

分 类 号：TQ203.2[化学工程—有机化工]