Pronounced interfacial interaction in icosahedral Au@C_(60) core-shell nanostructure for boosting direct plasmonic photocatalysis under alkaline condition  

作　　者：Yue Tian Qingqiang Cui Linlin Xu Anxin Jiao Shuang Li Xuelin Wang Ming Chen 

机构地区：[1]Institute of Frontier and Interdisciplinary Science,Shandong University,Qingdao 266237,China [2]School of Physics,Shandong University,Jinan 250100,China [3]School of Science,Shandong Jianzhu University,Jinan 250101,China

出　　处：《Journal of Materials Science & Technology》2021年第35期10-21,共12页材料科学技术（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(NSFC)(Nos.11905115,11575102);the Shandong Jianzhu University XNBS Foundation(No.1608);the Fundamental Research Fund of Shandong University(No.2018JC022)。

摘　　要：The unique hot carrier-driven direct plasmonic photocatalysis of coinage metal nanomaterials(NMs)via energetic localized surface plasmon resonance(LSPR)in visible-light region has been explored in recent years.However,the low photoinduced electron transfer efficiency and insufficient separation of electronhole pairs would severely preclude their widespread practical applications.Herein,we demonstrate an interesting plasmonic photocatalyst based on the construction of icosahedral(Ih)Au@C_(60) core-shell NMs,taking advantage of specific delocalizedπelectrons structure of a tight C_(60) shell and enhanced LSPR property of Ih Au core.Then,the pronounced interfacial interaction at junction region endows the obtained Au@C_(60) NMs with an outstanding photoinduced hot carrier-transmission during photocatalytic reaction,facilitating a remarkably higher(1.89 times)photocatalytic activity toward visible-light driven degradation of crystal violet(CV)dyes,as compared to bare Au NMs.Impressively,the photocatalytic activity of Ih Au@C_(60) NMs can be effectively optimized by changing the p H value of reaction solution,with the kinetic rate constant reaching the maximum value of 0.179 min^(-1) in pH011.4 solution,while 0.005 min^(-1) at pH03.0.Moreover,due to the protection of a tight C_(60) shell,the Ih Au@C_(60) NMs also possess excellent photocatalytic stability/reusability in recycling runs,holding great potential for the design of robust and high-performance plasmonic photocatalysts in repeated practical applications.

关 键 词：Direct plasmonic photocatalysis Icosahedral Au@C_(60)core-shell nanostructure Localized surface plasmon resonance Delocalizedπelectrons Photocatalytic degradation 

分 类 号：TB383.1[一般工业技术—材料科学与工程] O643.36[理学—物理化学] O644.1[理学—化学]