Facile Oxygen-promoted Synthesis of Cu,N Co-doped Carbon Composites for Oxygen Reduction  

作　　者：LIU Qianqian GUO Wei PAN Mu TU Wenmao 刘倩倩;GUO Wei;PAN Mu;涂文懋(Hubei Key Laboratory of Fuel Cell,Wuhan University of Technology,Wuhan 430070,China;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China)

机构地区：[1]Hubei Key Laboratory of Fuel Cell,Wuhan University of Technology,Wuhan 430070,China [2]State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2021年第6期796-803,共8页武汉理工大学学报（材料科学英文版）

基　　金：Funded in Part by the National Key Research and Development Program of China(2017YFB0102801)。

摘　　要：A new strategy to fabricate oxygen-promoted Cu,N co-doped carbon(OP-CuN@C)composites is reported.The strategy consists of only two simple steps:chemical polymerization and high temperature carbonization.Electrochemical measurements were conducted to investigate the catalytic activity and mechanism of ORR on the resulting samples.All the electrochemical results indicate that OP-CuN@C exhibits the best ORR catalytic activity.The ORR onset potential of OP-CuN@C is slightly lower than that of commercial Pt/C catalyst.The good performance is attributed to the large specific surface area,high content of heteroatoms(pyridinic,graphitic nitrogen,and oxygen atom)and synergistic effect between divalent copper and nitrogen dopant.

关 键 词：oxygen reduction reaction oxygen promotion OP-CuN@C chemical polymerization approach high temperature carbonized method 

分 类 号：TM911.4[电气工程—电力电子与电力传动] O643.36[理学—物理化学] TB332[理学—化学]