石墨炔界面:从微观到宏观电极优化策略  

Graphdiyne interface: electrode optimization strategy from microscale to macroscale

作　　者：成姝锦 左自成 李玉良[1] Shujin Cheng;Zicheng Zuo;Yuliang Li(Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China)

机构地区：[1]中国科学院化学研究所,北京100190

出　　处：《中国科学：化学》2022年第2期222-240,共19页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:22021002,51802311,U1932211,21790050,21790051);国家重点研发计划(编号:2018YFA0703501);中科院创新促进会(编号:2019032)资助项目。

摘　　要：石墨炔是新兴的二维碳同素异形体,其独特的结构和性质已经为绿色能源、绿色化学、生物医药、智能电子等领域带来诸多原创的理念.在电化学能源领域,石墨炔已经逐渐发展成为该领域中具有巨大发展潜力的关键材料之一,为解决电化学能源领域的诸多关键问题提供了新的思路.本文系统总结了利用石墨炔优异本征性质,解决目前电化学能源器件的瓶颈问题获得的研究进展,主要包括石墨炔抑制原子尺度的电极活性物质溶解穿梭与界面副反应、稳定纳米尺度的电极主体结构与次级结构、避免宏观尺寸的活性物质脱落和导电网络破坏等科学问题.结合研究进展进一步提出石墨炔作为电化学能源关键材料所面临的机遇和挑战.Graphdiyne is one of the emerging two-dimensional carbon allotropes, and its unique structure and properties have inspired many original concepts in the green energy, green chemistry, biomedical and intelligent electronic devices.In the field of electrochemical energy source, graphdiyne, as one of the key materials with great potential, shows many new ideas for solving the crucial issues in the electrochemical energy field. This review briefly summarizes recent progress in solving the bottleneck problems in electrochemical energy devices by the advantages of graphdiyne. It mainly contains the atomic-level suppression in the shuttle effect of active mass and the interfacial side reactions,stabilizing the primary and secondary structures in nanoscale, and avoiding the exfoliation of the active mass from substrate and the crack of the conductive network in macroscale. With the recent progress, the opportunities and challenges in using graphdiyne as the key materials for electrochemical energy sources are discussed.

关 键 词：石墨炔 电极界面 选择性传输 锂离子电池 燃料电池 

分 类 号：TQ127.11[化学工程—无机化工]