基于喹啉选择加氢反应的多相金属催化剂研究进展  

Progress on heterogeneous metal catalysts for selective hydrogenation of quinoline

作　　者：赵建波 袁海丰 谢冰 ZHAO Jian-bo;YUAN Hai-feng;XIE Bing(School of Material&Chemical Engineering,Zhengzhou University of Light Industry,Zhengzhou 450000,China)

机构地区：[1]郑州轻工业大学材料与化学工程学院,河南郑州450000

出　　处：《化学研究与应用》2022年第2期225-232,共8页Chemical Research and Application

基　　金：国家自然科学基金项目(21576248)资助;河南省高等学校重点科研项目(21A150057)资助;郑州轻工业大学博士基金项目(2014BSJJ007)。

摘　　要：喹啉选择加氢制备1,2,3,4-四氢喹啉是最为简便和可行的方法,后者是一种重要的精细化工中间体。本文综述了近10年基于喹啉及其衍生物选择加氢反应的多相金属催化剂研究进展,探讨了活性金属组分和载体对催化性能的影响。最后对该领域存在的问题和发展前景进行了总结和展望。The selective hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline is the most simple and powerful approach because the latter is an important kind of fine chemical intermediates.The progress on heterogeneous metal catalysts in the catalytic selective hydrogenation of quinoline and its derivatives in the last ten years is reviewed.The effect of active metal components and supports on the catalytic properties of heterogeneous metal catalysts are discussed.Finally,the urgent problems are summarized and future perspectives about hererogeneous metal catalysis of quinoline hydrogenation are pointed out.

关 键 词：喹啉 选择加氢 1 2 3 4-四氢喹啉 贵金属催化剂 非贵金属催化剂 

分 类 号：O643.38[理学—物理化学]