Oxidative Cross-Coupling Reactions between Two Nucleophiles  

作　　者：Lijun Lu Hao Li Aiwen Lei 

机构地区：[1]Institute for Advanced Studies(IAS),College of Chemistry and Molecular Sciences,Wuhan University,Wuhan,Hubei 430072,China

出　　处：《Chinese Journal of Chemistry》2022年第2期256-266,共11页中国化学（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(No.22031008);the Science Foundation of Wuhan(No.2020010601012192).

摘　　要：What is the most favorite and original chemistry developed in your research group?Oxidative Cross-Coupling-The chemistry between two"nucleophiles".How do you get into this specific field?Could you please share some experiences with our readers?My first contact with palladium chemistry was the halopalladation of acetylene in 1998.Then I worked on palladium enolate and found it could initiate a transmetalation reaction.Until 2006,I found that desyl chloride(a halogenated hydrocarbon)showed different reactivity with orga no metallic reagents due to the halophilic and oxyphilic properties,thus we achieved the cross-coupling between two orga no metallic reagents.

关 键 词：Oxidative cross-coupling Oxidation-induced Reaction mechanisms PHOTOCHEMISTRY ELECTROCHEMISTRY 

分 类 号：O62[理学—有机化学]