Thermal Polymerization of Cyanate Ester-Benzoxazine:Study of a Functional Model Compound  

作　　者：WANG Fan ZHOU Hui WAN Li DONG Bin LI Shengchao QI Huimin 

机构地区：[1]Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China [2]Shanghai Composites Science&Technology Co.,Ltd.,Shanghai 201112,China

出　　处：《上海航天（中英文）》2022年第1期122-128,161,共8页Aerospace Shanghai（Chinese&English）

摘　　要：A novel benzoxazine(BOZ)monomer is synthesized by a pot method with solvent-free to blend with cyanate ester(CE).A soluble intermediate is obtained after being cured for 20 h at 80℃.The two model compound and the blends are analyzed with the infrared radiation(IR),nuclear magnetic resonance(NMR)spectroscopy,and differential scanning calorimetry(DSC).The results show that an intermediate of the iminocarbonate and BOZ structures is formed by the ring-open BOZ reacting with the cyanate groups and ring-unopened BOZ.Moreover,rearrangement and ring-opening occur in the postcure of the intermediate to form the alkyl isocyanurate structure with polybenzoxazine.

关 键 词：thermosetting resin benzoxazine(BOZ) cyanate ester(CE)resin polymerization mechanism 

分 类 号：TB3[一般工业技术—材料科学与工程]