甲醇重整制氢燃料电池发电研究进展  

Research Progress of Hydrogen Production by Methanol Reforming for Fuel Cell Power Generation

作　　者：李林[1,2] 刘彤宇 李爽 史翊翔[1,2] 蔡宁生 LI Lin;LIU Tongyu;LI Shuang;SHI Yixiang;CAI Ningsheng(Key Laboratory for Thermal Science and Power Engineering of Ministry of Education(Department of Energy and Power Engineering,Tsinghua University),Haidian District,Beijing 100084,China;Shanxi Research Institute for Clean Energy,Tsinghua University,Taiyuan 030032,Shanxi Province,China)

机构地区：[1]热科学与动力工程教育部重点实验室(清华大学能源与动力工程系),北京市海淀区100084 [2]清华大学山西清洁能源研究院,山西省太原市030032

出　　处：《发电技术》2022年第1期44-53,共10页Power Generation Technology

基　　金：国家自然科学基金项目(51806120);清华大学-丰田联合研究基金专项;清华大学山西清洁能源研究院科研团队经费(sxky1903)。

摘　　要：质子交换膜燃料电池具有效率高、无污染、燃料适应性好等优点,其与可靠制氢相结合形成的绿色能源网络是实现碳中和的有效途径,有望推进以氢燃料电池为电、热动力来源的新能源汽车、无人机、船舶等产业的技术研发与升级。然而,安全稳定的氢气供给技术是限制基于移动场景下的燃料电池发电应用发展的主要瓶颈,采用甲醇原位重整制氢有望在燃料电池移动氢源问题上实现突破。为此,从甲醇重整制氢研究进展、甲醇重整制氢反应器研究进展以及甲醇重整燃料电池发电应用等方面进行了综述,以期为促进甲醇重整燃料电池在新能源领域的商业化发展与应用提供一定的参考和指导。Proton exchange membrane fuel cells take advantages of high efficiency,no pollution and good fuel adaptability.The green energy network formed by combining fuel cells with reliable hydrogen production is an effective way to achieve carbon neutrality.It is expected to promote the technological research and upgrading of new energy vehicles,unmanned air vehicles,ships and other industries those use fuel cells as electricity and thermal power source.However,a safe and stable hydrogen supply technology is a major bottleneck limiting the development of fuel cell power generation applications in mobile scenarios.Hydrogen production by in-situ methanol reforming is hopeful to make a breakthrough in mobile hydrogen source technology based on fuel cell.In this paper,the research progress of methanol reforming hydrogen production,the research progress of reactors for methanol reforming hydrogen production and the application of methanol reforming fuel cell power generation system were reviewed to provide reference and guidance for promoting the commercial development and application of methanol reforming fuel cell in the field of new energy.

关 键 词：碳中和 甲醇重整制氢 燃料电池发电 催化剂 反应器 

分 类 号：TK91[动力工程及工程热物理]