顶空-气相色谱质谱法测定颜料类产品中10种苯系物含量  

Determination of 10 Benzene Solvents in Pigment Products by HeadspaceGas Chromatography-mass Spectrometry

作　　者：赵晓甫 张蓓 ZHAO Xiao-fu;ZHANG Bei(l.Hebei Academy of Product Quality Supervision&Inspection;China National Center for Quality Supervision and Test of Environmental Protection Products)

机构地区：[1]河北省产品质量监督检验研究院 [2]国家环保产品质量监督检验中心

出　　处：《中国标准化》2022年第4期240-245,共6页China Standardization

基　　金：河北省市场监督管理局科研项目(编号:2020ZC17)资助。

摘　　要：采用外标法定量,建立了顶空-气相色谱质谱法测定颜料类产品中10种苯系物含量的试验方法。实验结果表明,该方法在0.3~10.0 mg/kg范围内线性良好(r^(2)>0.9995),检出限均为0.1mg/kg。按照建立的方法进行了三个不同添加量加标回收试验,回收率为92.9%~104.4%,测定值的相对标准偏差(RSD)为0.58%~5.73%(n=6)。In this paper,a method for the determination of 10 benzene solvents in pigment products by HS-GC-MS is established.The experimental results show that the method has good linearity in the range of 0.3~10.0 mg/kg(r^(2)>0.9995),and the detection limits are all 0.1 mg/kg.According to the established method,three recovery tests are carried out.The recoveries range from 92.0%to 103.3%,and the relative standard deviation(RSD)is 0.58%~5.73%(n=6).

关 键 词：顶空-气相色谱质谱法 颜料类产品 苯系物 

分 类 号：O657.63[理学—分析化学] TQ620.72[理学—化学]