聚集诱导发光  

Aggregation-Induced Emission

作　　者：韩鹏博 徐赫 安众福[2] 蔡哲毅 蔡政旭 巢晖 陈彪 陈明 陈禹 池振国 代淑婷 丁丹[8] 董宇平 高志远 管伟江[9] 何自开 胡晶晶 胡蓉 胡毅雄 黄秋忆 康苗苗 李丹霞 李济森 李树珍 李文朗 李振[15,16] 林新霖[4] 刘骅莹 刘佩颖 娄筱叮 吕超 马东阁[1] 欧翰林 欧阳娟 彭谦 钱骏 秦安军[1] 屈佳敏 石建兵 帅志刚 孙立和[1] 田锐 田文晶[7] 佟斌[3] 汪辉亮 王东 王鹤 王涛 王晓 王誉澄 吴水珠 夏帆 谢育俊 熊凯 徐斌 闫东鹏[14] 杨海波 杨清正 杨志涌 袁丽珍 袁望章 臧双全[24] 曾钫[1] 曾嘉杰 曾卓 张国庆 张晓燕 张学鹏 张艺 张宇凡 张志军 赵娟 赵征 赵子豪 赵祖金 唐本忠 Pengbo Han;He Xu;Zhongfu An;Zheyi Cai;Zhengxu Cai;Hui Chao;Biao Chen;Ming Chen;Yu Chen;Zhenguo Chi;Shuting Dai;Dan Ding;Yuping Dong;Zhiyuan Gao;Weijiang Guan;Zikai He;Jingjing Hu;Rong Hu;Yixiong Hu;Qiuyi Huang;Miaomiao Kang;Danxia Li;Jisen Li;Shuzhen Li;Wenlang Li;Zhen Li;Xinlin Lin;Huaying Liu;Peiying Liu;Xiaoding Lou;Chao Lu;Dongge Ma;Hanlin Ou;Juan Ouyang;Qian Peng;Jun Qian;Anjun Qin;Jiamin Qu;Jianbing Shi;Zhigang Shuai;Lihe Sun;Rui Tian;Wenjing Tian;Bin Tong;Huiliang Wang;Dong Wang;He Wang;Tao Wang;Xiao Wang;Yucheng Wang;Shuizhu Wu;Fan Xia;Yujun Xie;Kai Xiong;Bin Xu;Dongpeng Yan;Haibo Yang;Qingzheng Yang;Zhiyong Yang;Lizhen Yuan;Wangzhang Yuan;Shuangquan Zang;Fang Zeng;Jiajie Zeng;Zhuo Zeng;Guoqing Zhang;Xiaoyan Zhang;Xuepeng Zhang;Yi Zhang;Yufan Zhang;Zhijun Zhang;Juan Zhao;Zheng Zhao;Zihao Zhao;Zujin Zhao;Ben Zhong Tang(State Key Laboratory of Luminescent Materials and Devices,Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,Center for Aggregation-Induced Emission,South China University of Technology,Guangzhou 510640,China;Key Laboratory of Flexible Electronics&Institute of Advanced Materials,Nanjing Tech University,Nanjing 211816,China;Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications,School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China;MOE Key Laboratory of Bioinorganic and Synthetic Chemistry,School of Chemistry,Sun Yat-Sen University,Guangzhou 510006,China;Hefei National Laboratory for Physical Sciences at the Microscale,University of Science and Technology of China,Hefei 230026,China;College of Chemistry and Materials Science,Jinan University,Guangzhou 510632,China;State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012;State Key Laboratory of Medicinal Chemical Biology,Key Laboratory of Bioactive Materials,Ministry of Education,College of Life Sciences,Nankai University,Tianjin 300071,China;State Key Laboratory of Ch

机构地区：[1]华南理工大学材料科学与工程学院,发光材料与器件国家重点实验室,聚集诱导发光中心,广东省分子聚集发光重点实验室,广州510640 [2]南京工业大学先进材料研究院,南京211816 [3]北京理工大学材料学院结构可控先进功能材料与绿色应用北京市重点实验室,北京100081 [4]中山大学化学学院生物无机与合成化学教育部重点实验室,广州510006 [5]中国科学技术大学合肥微尺度物质科学国家研究中心,合肥230026 [6]暨南大学化学与材料学院,广州510632 [7]吉林大学化学学院超分子结构与材料国家重点实验室,长春130012 [8]南开大学生命科学学院药物化学与生物学国家重点实验室,生物活性材料教育部重点实验室,天津300071 [9]北京化工大学化工资源有效利用国家重点实验室,北京100029 [10]哈尔滨工业大学(深圳)理学院,深圳518055 [11]中国地质大学(武汉)材料与化学学院生物地质与环境地质国家重点实验室,武汉430074 [12]华东师范大学化学与分子工程学院,上海市绿色化学与化工过程绿色化重点实验室,上海200062 [13]深圳大学材料学院AIE研究中心,深圳518055 [14]北京师范大学化学学院能量转换与存储材料北京市重点实验室,北京100875 [15]天津大学分子聚集态科学研究院,天津300192 [16]武汉大学化学与分子科学学院,武汉430072 [17]中国科学院大学化学科学学院,北京101804 [18]浙江大学光电科学与工程学院,现代光学仪器国家重点实验室,先进光子学国际研究中心,光及电磁波研究中心,杭州310058 [19]清华大学化学系,北京100084 [20]西北工业大学柔性电子研究院生物医学材料与工程研究所,西安710072 [21]香港中文大学(深圳)理工学院深圳分子聚集体科学与工程研究院,深圳518172 [22]北京师范大学化学学院放射性药物教育部重点实验室,北京100875 [23]上海交通大学化学化工学院变革性分子前沿科学中�

出　　处：《化学进展》2022年第1期1-130,共130页Progress in Chemistry

基　　金：国家自然科学基金项目(No.21788102,21977126,21907112,21778079,51961160730,51873092,81921004,21975238,21974008,21838007,21804006,51733010,21875019,21975020,21975021,21975061,22090050,21974128,21874121,52003257,21973099,21905113,21835001,51773080,21674041,51903163,21801169,21875069,21625202,21971023,51822303,52073172,21574015,52003228,92061201,21825106,21771021,21822501,22061130206,61975172,82001874,51620105009);广东省自然科学基金(No.2021B1515020102,2020B1515020011,2016A030312002);国家重点研发计划中国-澳大利亚政府间国际科技创新合作项目(No.2017YFE0132200);国家重点研发计划(No.2017YFA0303500);广东省分子聚集发光重点实验室基金(No.2019B030301003);深圳市自然科学基金(No.JCYJ20190808153415062);中央高校基本科研专项资金(No.2020-KYY-511108-0007);中国博士后科学基金(No.2019M653036);中国科学技术大学启动经费(No.KY2340000139);香港创新科技委员会(No.ITC-CNERC14S01)资助

摘　　要：聚集诱导发光(AIE)是唐本忠院士于2001年提出的一个科学概念,是指一类在溶液中不发光或者发光微弱的分子聚集后发光显著增强的现象。高效固态发光的AIE材料有望从根本上解决有机发光材料面临的聚集导致发光猝灭难题,具有重大的实际应用价值。从分子内旋转受限到分子内运动受限,从聚集诱导发光到聚集体科学,AIE领域已经取得了许多原创性的成果。在本综述中,我们从AIE材料的分类、机理、概念衍生、性能、应用和挑战等方面讨论了AIE领域最近取得的显著进展。希望本综述能激发更多关于分子聚集体的研究,并推动材料、化学和生物医学等学科的进一步交叉融合和更大发展。Aggregation-induced emission (AIE), conceptually coined by Prof. Ben Zhong Tang in 2001, refers to a unique photophysical phenomenon non- or weakly emissive luminogens in dilute solutions emit intensely upon aggregation. AIE can solve the aggregation-caused quenching problem that traditional fluorophores are suffering from and hold great technological values for practical applications. The past 20 years have witnessed the rapid development of AIE research, from the restriction of intramolecular rotations to restriction of intramolecular motions, and from AIE to aggregate science, and many original results have been achieved. In this review, we summarize the advances in the field of AIE and its related areas. We specifically discuss the recent progress in AIE area, including material classification, mechanism, concept derivation, property, applications, and challenges. It is hoped that this review will inspire more research into the molecular aggregate level and make significant advances in materials, chemistry and biological sciences.

关 键 词：聚集诱导发光 聚集体科学 分子内运动受限 

分 类 号：O644[理学—物理化学] O657.3[理学—化学]