生物质基糠醛和5-羟甲基糠醛加氢转化研究进展  

Advances on the catalytic hydrogenation of biomass-derived furfural and 5-hydroxymethylfurfural

作　　者：张军[1,2,3,4] 李丹妮 袁浩然[1,2,3,4] 王树荣 陈勇[1,2,3,4] ZHANG Jun;LI Dan-ni;YUAN Hao-ran;WANG Shu-rong;CHEN Yong(Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences(CAS),Guangzhou 510640,China;Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou),Guangzhou 511458,China;CAS Key Laboratory of Renewable Energy,Guangzhou 510640,China;Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development,Guangzhou 510640,China;State Key Laboratory of Clean Energy Utilization,Zhejiang University,Hangzhou 310027,China)

机构地区：[1]中国科学院广州能源研究所,广东广州510640 [2]南方海洋科学与工程广东省实验室(广州),广东广州511458 [3]中国科学院可再生能源重点实验室,广东广州510640 [4]广东省新能源和可再生能源研究开发与应用重点实验室,广东广州510640 [5]浙江大学能源清洁利用国家重点实验室,浙江杭州310027

出　　处：《燃料化学学报》2021年第12期1752-1767,共16页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金面上项目(51976222);南方海洋科学与工程广东省实验室(广州)人才团队引进重大专项(GML2019ZD0101);能源清洁利用国家重点实验室开放基金课题(ZJU-CEU2020023)资助。

摘　　要：近年来,利用生物质基平台化合物转化制备各种燃料及高值化学品引起研究人员的广泛关注。5-羟甲基糠醛(HMF)和糠醛(FFR)作为一类重要的生物质衍生平台化合物,分子结构中醛基和呋喃环等官能团赋予其独特的化学性质。本综述针对HMF和FFR在氢气、低碳醇、甲酸和硅烷等不同氢源中的催化加氢反应研究现状进行了阐述,对加氢转化过程中的主要影响因素如催化剂类型和反应条件以及反应机理等进行了详细分析,同时对HMF/FFR加氢转化应用研究前景进行了展望。In recent years,the conversion of biomass-derived platform compounds into a variety of high value fuel and chemical products has attracted increasing attention from researchers.5-Hydroxymethylfurfural(HMF)and furfural(FFR)belong to a class of important biomass-derived platform chemicals.The molecular structure of HMF and FFR is consisted of aldehyde group,furan ring and other functional groups,which endow them with unique chemical properties.In this paper,the research advances on the catalytic hydrogenation of HMF and FFR using various hydrogen sources,such as hydrogen,alcohol,silanes and formic acid,have been reviewed in detail.In addition,the main influencing factors like catalyst type and reaction conditions on the hydrogenation process as well as the reaction mechanism are discussed in depth.Meanwhile,research foreground in the catalytic hydrogenation of HMF/FFR has been prospected.

关 键 词：生物质 催化加氢 5-羟甲基糠醛 糠醛 

分 类 号：TQ251.1[化学工程—有机化工]