A facile,scalable,high stability Lithium metal anode  被引量:4

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作  者:Qiang Zhao Xin Chen Wang Hou Beirong Ye Yongqi Zhang Xinhui Xia Jinshu Wang 

机构地区:[1]School of Materials and Energy,University of Electronic Science and Technology of China,Chengdu,P.R.China [2]Yangtze Delta Region Institute(Huzhou),University of Electronic Science and Technology of China,Huzhou,P.R.China [3]Institute of Fundamental and Frontier Sciences,University of Electronic Science and Technology of China,Chengdu,Sichuan,P.R.China [4]State Key Lab of Silicon Materials,Zhejiang University,Hangzhou,P.R.China

出  处:《SusMat》2022年第1期104-112,共9页可持续发展材料(英文)

基  金:National Key Research and Development Program of China,Grant/Award Number:2017YFA0701001;Fundamental Research Founds for the CentralUniversities,Grant/Award Number:ZYGX2019J024;National Natural Science Foundation of China,Grant/Award Number:52002052。

摘  要:Li has garnered enormous attention for next-generation Limetal batteries owing to its remarkable theoretical capacity.Unfortunately,as an anode,Li suffers from serious safety issues and fast capacity fading due to the formation of Li dendrites,which hinders the practical application of Li anode.Herein,a LiAlO_(2)-PVDF composite modification layer is fabricated on the surface of Li metal to enhance its stability and electrochemical performance.Benefitting fromthe synergetic effects of high Li+conductivity,high Li+transference number,excellent mechanical properties,superior chemical durability,and compactness of the modification layer,the LiAlO_(2)-PVDF@Li electrode delivers an ultra-long lifespan and a high capacity retention rate in the LiAlO2-PVDF@Li│LiFePO_(4) full cell.The proposed strategy provides a new alternative anode for Li metal batteries with high performance and scalable production.

关 键 词:Artificial modification layer Li metal anode LiAlO2-PVDF SPIN-COATING 

分 类 号:TM9[电气工程—电力电子与电力传动]

 

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