A chrome-free combination tanning strategy: based on silicic acid and plant tannin  

作　　者：Zetian Zhang Yang Liu Junchao Wang Taoling Xie Liying Sun Zhengjun Li 

机构地区：[1]National Engineering Research Center of Clean Technology in Leather Industry,Sichuan University,Chengdu 610065,China [2]Key Laboratory of Leather Chemistry and Engineering of Ministry of Education,Sichuan University,Chengdu 610065,China

出　　处：《Journal of Leather Science and Engineering》2021年第1期166-178,共13页皮革科学与工程（英文）

基　　金：This research was supported by the National Natural Science Foundation of China(No.21376153);the Fundamental Research Funds for the Central University of China,and Sichuan University-Zschimmer&Schwarz CmbH&Co.KG Scholarships(2020).

摘　　要：Silicic acid,commonly derived from cheap and easily available sodium silicate,has recently received great attention for application in leather industry to produce ecological leather with a cleaner approach.However,leather tanned with silicic acid alone is poor in storage stability,which limits its practical application in leather production.In this work,a new environment-friendly combination tannage based on silicic acid and plant tannin was developed to address this issue along with improving the comprehensive performances of leather.The obtained leather was characterized by scanning electron microscopy,Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and so on.The results showed that compared with leather tanned with silicic acid alone,the leather tanned with this combination method possessed improved thermal stability,enhanced mechanical properties,acceptable softness,appropriate hydrophilicity,and especially enhanced storage stability.More importantly,the combination tanned leather with 1:1 of the mass ratio of silicic acid to vegetable tannin(composed of valonea extract and mimosa extract with the same weight)had more prominent comprehensive performances.In addition,the results demonstrated that hydrogen bonding played an important role in the combination tanning process.Furthermore,the hydrogen bonds generated between phenolic hydroxyl groups of polyphenols with silicon hydroxyl groups of silicic acid molecules inhibited the excessive condensation of Si-OH groups between themselves.Subsequently,the assessment of environmental impact revealed the value of BOD 5/COD of the wastewater produced in this combination tanning process is more than 0.3,indicating the chrome-free combination tannage based on silicic acid and plant tannin was an environment-friendly tanning technology.These findings therefore indicated that a new chrome-free tanning method with silicon and biomass materials as main tanning agents has potential practical application prospect in leather production.

关 键 词：Silicic acid Plant tannin Chrome-free tannage Storage stability ENVIRONMENT-FRIENDLY 

分 类 号：TS5[轻工技术与工程—皮革化学与工程]