萘酚吡喃-姜黄素光致变色荧光开关分子的合成与性能研究  

The synthesis and properties of photochromic fluorescence switching based on the naphthopyran-curcumin

作　　者：孙娥 王广[1] SUN E;WANG Guang(Faculty of Chemistry,Northeast Normal University,Changchun 130024,China)

机构地区：[1]东北师范大学化学学院,吉林长春130024

出　　处：《东北师大学报（自然科学版）》2022年第1期94-98,共5页Journal of Northeast Normal University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(50873019).

摘　　要：设计合成了含有萘酚吡喃和姜黄素的光致变色荧光开关分子.在聚甲基丙烯酸甲酯(PMMA)薄膜中基于能量转移机理通过萘酚吡喃的光致变色行为实现了对姜黄素荧光强度的调节,即荧光的"开/关".荧光图像变化进一步证实了萘酚吡喃的光致变色开关环反应能够可逆地调节姜黄素的荧光强度.The photochromic fluorescence switching based on the naphthopyran-curcumin compound was designed and synthesized.The fluorescence intensity of curcumin can be modulated between “on” and “off” by the photochromic behaviors of naphthopyran in the doped PMMA film based on the photoinduced energy transfer mechanism.The fluorescent images further proved that the ring-open reaction of naphthopyran can modulate the fluorescent intensity of curcumin.

关 键 词：荧光开关 光致变色 萘酚吡喃 姜黄素 

分 类 号：O62[理学—有机化学]