生物油催化重整制氢研究进展  

Research progress of hydrogen production by catalytic reforming of bio-oil

作　　者：方书起[1,2,3] 王毓谦 李攀 陈志勇[2] 陈玮 白净 常春 FANG Shuqi;WANG Yuqian;LI Pan;CHEN Zhiyong;CHEN Wei;BAI Jing;CHANG Chun(School of Mechanical and Power Engineering,Zhengzhou University,Zhengzhou 450001,Henan,China;Henan Key Laboratory of Green Manufacturing of Biobased Chemicals,Puyang 457000,Henan,China;Engineering Laboratory of Henan Province for Biorefinery Technology and Equipment,Zhengzhou 450001,Henan,China)

机构地区：[1]郑州大学机械与动力工程学院,河南郑州450001 [2]河南省生物基化学品绿色制造重点实验室,河南濮阳457000 [3]生物质炼制技术与装备河南省工程实验室,河南郑州450001

出　　处：《化工进展》2022年第3期1330-1339,共10页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(52006200,22178328);低品位能源利用技术及系统教育部重点实验室开放基金(LLEUTS-202219);煤燃烧国家重点实验室开放基金(FSKLCCA2108)。

摘　　要：随着各国新能源行业的兴起,氢能成为最具发展潜力的可再生能源。利用生物油进行催化重整是一种优良、高效的制氢方法,同时拓宽了生物油高值化利用的途径。本文对近年来该领域内的相关研究进行综述,重点介绍了原料对重整反应的影响(不同来源生物油及其模化物)、催化剂特性对重整反应的影响(负载贵金属与非贵金属)以及操作条件对重整反应的影响,对新兴的微波催化重整技术进行了简要介绍,并针对目前该领域所面临的困难提出了一些展望及发展方向,为生物油催化重整制氢提供重要理论依据。With the rise of new energy industry in various countries,hydrogen energy has become the most potential renewable energy.Catalytic reforming of bio-oil is an excellent and efficient method for hydrogen production and it broadens the way of high-value utilization of bio-oil.This article reviews the related research in this field in recent years,focusing on the effects of raw materials on the reforming reaction(different sources of bio-oil and its models),the effects of catalyst characteristics on the reforming reaction(loaded precious and non-precious metals),and the effects of operating conditions on the reforming reaction.The microwave catalytic reforming technology is briefly introduced.In view of the difficulties faced in this field,some prospects and development directions are put forward,which provides an important theoretical basis for the field of hydrogen production by catalytic reforming of bio-oil.

关 键 词：生物油 模型化合物 催化剂 制氢 

分 类 号：TK6[动力工程及工程热物理—生物能]