Constitutionally adaptive crown ether-based macrocyclic bolaamphiphile with redox-responsive switching of lower critical solution temperature behaviors  

作　　者：Qiangqiang Xu Zhiliyu Cui Jizhen Yao Bo Li Ping Lv Xin Shen Zhuo Yu Yan Ge Zhenhui Qi 

机构地区：[1]Sino-German Joint Research Lab for Space Biomaterials and Translational Technology,Synergetic Innovation Center of Biological Optoelectronics and Healthcare Engineering(BOHE),Xi'an 710072,China

出　　处：《Chinese Chemical Letters》2021年第12期4024-4028,共5页中国化学快报（英文版）

基　　金：the financial support from the National Natural Science Foundation of China (Nos. 52001255, 21901209, 21901210, 22071196, 22007078);Key R&D Program of Shaanxi Province (No. 2021KWZ-18);Aeronautical Science Foundation of China (No. ASFC-2020Z061053001);Fundamental Research Funds for the Central Universities (Nos. 3102019smxy001, 3102019ghxm005);Fellowship from CSC Innovative Team Program (No. CXXM20190099)。

摘　　要：Constitutionally adaptive chemistry of selenium-containing crown ethers(CEs) offers a new platform for controlling/switching the hydration of bolaamphiphile skeletons in water in an effective and simple manner by the virtue of covalent bonding. The adaptive behaviour of the macrocyclic bolaamphiphiles(transformations between C7SeBola and C7SeOBola) in response to redox environment was found to be a decisive factor.

关 键 词：MACROCYCLE Crown ether Bola Amphiphiles SELENIUM 

分 类 号：O641.3[理学—物理化学]