Dearomative spirocyclization via visible-light-induced reductive hydroarylation of non-activated arenes  

作　　者：Zhuomin Chi Yuzhen Gao Lei Yang Chunlin Zhou Meng Zhang Peiming Cheng Gang Li 

机构地区：[1]College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350117,China [2]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology,Center for Excellence in Molecular Synthesis,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China

出　　处：《Chinese Chemical Letters》2022年第1期225-228,共4页中国化学快报（英文版）

基　　金：the financial supports from the National Natural Science Foundation of China(Nos.22022111,21871257,21801240);the Natural Science Foundation of Fujian Province(No.2020J02008);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)。

摘　　要：A visible-light-induced spirocyclizative hydroarylation via reductive dearomatization of a series of non activated arenes including 2-phenyl indoles and naphthalene derivatives under mild conditions is de scribed.An intriguing chemoselective dearomative hydroarylation of 2-phenyl indoles is presented.Th dearomative hydroarylation protocol rapidly delivers valuable spirocycles with carbon-carbon doub bonds from readily accessible aromatic precursors in a single step.

关 键 词：Visible-light-induced Non-activated arene SPIROCYCLIZATION Dearomatization Reductive hydroarylation 

分 类 号：O621.25[理学—有机化学]