羟基硅油改性环氧树脂富镁底漆的制备与性能研究  

Properties of Hydroxy Silicone Oil-modified Epoxy Resin and Magnesium-rich Primer

作　　者：戈成岳[1,2] 罗祥平 王静 王宁[1] 段继周[1] 侯保荣[1] Ge Chengyue;Luo Xiangping;Wang Jing;Wang Ning;Duan Jizhou;Hou Baorong(Institute of Oceanology,Chinese Academy of Sciences,Key Laboratory of Marine Environmental Corrosion and Bio-Fouling of Chinese Academy of Sciences,Qingdao,Shandong 266071,China;Open Studio for Marine Corrosion and Protection,Pilot National Laboratory for Marine Science and Technology(Qingdao),Qingdao,Shandong 266237,China;Beijing Gas Group Co.,Ltd.,Beijing 100035,China)

机构地区：[1]中国科学院海洋研究所中国科学院海洋环境腐蚀与生物污损重点实验室,山东青岛266071 [2]青岛海洋科学与技术试点国家实验室海洋腐蚀与防护开放工作室,山东青岛266237 [3]北京市燃气集团有限责任公司,北京100035

出　　处：《涂料工业》2022年第3期24-30,共7页Paint & Coatings Industry

基　　金：中国科学院南海生态环境工程创新研究院创新发展基金项目(ISEE2018YB05);山东省中央引导地方科技发展资金项目(YDZX20203700002831);科技部重点研发计划(2019YFC0312103)。

摘　　要：研究了一种羟基硅油改性环氧树脂的方法,通过红外光谱、GPC测试、DSC测试以及稳定性分析详细考察了反应物配比对改性树脂性能的影响。研究表明:羟基硅油和环氧树脂质量比为5∶1的体系获得的改性产物稳定性好,且具有高的柔韧性和强度;进一步,利用改性树脂配制羟基硅油改性环氧-富镁底漆,通过涂层基本性能测试,盐雾试验和老化试验研究了涂层对铝合金的保护性能。研究表明:涂层附着力得到改善,柔韧性和耐冲击性提高,耐盐雾性优异,耐老化性一般,需与面漆配套使用。A modified method of epoxy resin by hydroxy silicone was studied in this paper,the influence of reactant ratio on the properties of modified resin was investigated in detail through infrared spectroscopy,GPC test,DSC test and stability analysis. The result showed that when a ratio of hydroxy silicone oil and epoxy resin was 5∶1(mass ratio),the modified products had good stability,high flexibility and strength. Further,using the modified resin to prepare magnesium-rich primer,then protective performance of the coating on aluminum alloy was studied through the basic performance test,salt spray test and aging test.The result showed that adhesion of coating was improved,flexibility and impact resistance were better,the salt spray resistance was superior,and the aging resistance was mediocre,so it need to be used in conjunction with topcoat.

关 键 词：富镁底漆 羟基硅油 改性环氧树脂 铝合金 

分 类 号：TQ630.43[化学工程—精细化工]