堆存温度对半水磷石膏胶凝性能影响  

Effect of storage temperature on the cementitious property of hemihydrate phosphogypsum

作　　者：王志凯 王贻明[1] 吴爱祥[1] 李根 李剑秋 WANG Zhi-kai;WANG Yi-ming;WU Ai-xiang;LI Gen;LI Jian-qiu(School of Civil and Resources Engineering,University of Science and Technology Beijing,Beijing 100083,China;School of Chemistry and Chemical Engineering,Guizhou University,Guiyang 550025,China)

机构地区：[1]北京科技大学土木与资源工程学院,北京100083 [2]贵州大学化学与化工学院,贵阳550025

出　　处：《工程科学学报》2022年第5期840-848,共9页Chinese Journal of Engineering

基　　金：国家自然科学基金资助项目(51674012)。

摘　　要：半水磷石膏(HPG)长时间堆存状态下会出现固结现象,其胶凝性能也相应下降.以室内HPG结晶水检测和单轴压缩试验为基础,通过设定4种不同堆存温度,分别为20,40,60和80℃,探究不同堆存温度作用下HPG试样结晶水质量分数变化和堆存后制备的充填胶凝材料(HCM)抗压强度发展规律,并采用扫描电镜等微观分析手段研究堆存温度对其强度影响机制.结果表明,堆存温度对HPG胶凝性能影响显著,高的堆存温度会加快HPG试样中的自由水转变为结晶水速率,而且会抑制堆存后制备的HCM强度发展.采用数据标准化对不同堆存温度作用后的试样抗压强度作出预测,被证实与实测值较吻合.微观分析发现,堆存温度主要影响体系的过饱和度,而使不同堆存温度作用后制备的HCM微观形态表现差异.Whether domestic or foreign,the utilization of phosphogypsum(PG)resources is not satisfactory.A chemical plant in Guizhou produces phosphoric acid through a semi-aqueous process to obtain the byproduct hemihydrate phosphogypsum(HPG),which has a certain gelling activity.If this feature of HPG can be fully utilized,it can replace cement as a cementing material to prepare minefilling materials.Utilizing HPG for goaf filling can not only reduce the environmental protection problems caused by the surface discharge of PG but also eliminate the hidden safety hazards in the goaf.At present,when HPG is used to prepare mine-filling cementitious materials,HPG will be consolidated into a block and lose its gelling activity when it is stacked for a certain period of time.The gelling performance of the HPG in the storage state appears to decline.Based on the indoor HPG crystal water detection and uniaxial compression test and setting four different storage temperatures(20℃,40℃,60℃,and 80℃),this study explored the changes in the mass fraction of the crystal water of HPG samples under different storage temperatures.The compressive strength development law of HCM prepared after storage and microscopic analysis methods,such as scanning electron microscopy,were used to study the influence mechanism of the storage temperature on its strength.Results show that the stacking temperature has a significant effect on the gelling performance of HPG.A high stacking temperature will speed up the conversion of free water in the HPG sample to crystal water and inhibit the strength development of the HCM prepared after stacking.Data standardization was used to predict the compressive strength of samples after storage at different temperatures,which is confirmed to be in good agreement with the measured values.The microscopic analysis found that the storage temperature mainly affects the supersaturation of the system,and the microscopic morphology of the HCM prepared after storage at different temperatures is different.

关 键 词：半水磷石膏 堆存温度 胶凝性能 标准化处理 强度预测 

分 类 号：TD853[矿业工程—金属矿开采]