低泡沫环氧丙烷封端FMEE的合成与性能研究  

Synthesis and properties of low-foaming FMEE containing propylene oxide

作　　者：唐安喜 TANG An-xi(Shanghai Xihe Fine Chemical Co.,Ltd.,Shanghai 201620,China)

机构地区：[1]上海喜赫精细化工有限公司,上海201620

出　　处：《精细与专用化学品》2022年第3期38-41,共4页Fine and Specialty Chemicals

摘　　要：以十六碳脂肪酸为起始原料,采用无水三氧化二铝和氧化钡为二元催化剂,先与环氧乙烷发生聚合反应,再用环氧丙烷(PO)封端,最后通过甲基化反应引入末端甲基,得到的PO封端的脂肪酸甲酯乙氧基化物(FMEE)。通过核磁共振与红外吸收光谱分析,确定PO封端FMEE的结构并测试相关性能指标。结果表明,PO封端FMEE具有低泡沫、低温流动性好的特点。Hexadecane fatty acid was polymerized with ethylene oxide and propylene oxide in condition of anhydrous Al;O;and BaO as binary catalysts, methyl was introduced through methylation reaction.The structure of the product was determined by the nuclear magnetic resonance and Infrared spectrometry analysis.The test data show that FMEE containing propylene oxide has the excellent ability of low-foam and low-temperature liquidity.

关 键 词：甲基化 PO封端 FMEE 低泡沫 

分 类 号：TQ423[化学工程]