愈创木酚/癸二胺型苯并[口恶]嗪增韧双酚A-苯胺型[口恶]嗪树脂的研究  

Preparation of bisphenol A-type benzoxazine resin toughened by guaiacol/1,10-diaminodecane based benzoxazine

作　　者：梁佩茵 张倩 徐日炜[3] Liang Peiyin;Zhang Qian;Xu Riwei(Guangdong Provincial Key Laboratory of Optical Information Materials and Technology&Institute of Electronic Paper Displays,South China Academy of Advanced Optoelectronics,South China Normal University,Guangzhou 510006;Ablestik Shanghai Co.,Ltd.,Shanghai 200131;Key Laboratory of Carbon Fiber and Functional Polymers,Ministry of Education,Beijing University of Chemical Technology,Beijing 100029)

机构地区：[1]华南师范大学,华南先进光电子研究院,广东省光信息材料与技术重点实验室&彩色动态电子纸显示技术研究所,广州510006 [2]爱博斯迪科化学(上海)有限公司,上海200131 [3]北京化工大学碳纤维及功能高分子教育部重点实验室,北京100029

出　　处：《化工新型材料》2022年第3期84-88,共5页New Chemical Materials

基　　金：国家自然科学基金资助项目(51573009);广东省光信息材料与技术重点实验室(2017B030301007)。

摘　　要：采用来源于可再生资源的愈创木酚、癸二胺和多聚甲醛等为原料合成了愈创木酚-癸二胺型苯并嗪单体(G-d),通过红外光谱、凝胶渗透色谱、核磁共振氢谱证明了其分子结构。差热扫描分析和热重分析测试结果表明,其树脂的起始固化温度为225℃,峰值固化温度为246℃。通过热固化工艺得到自固化产物PG-d,并研究其热固化行为、动态力学性能和热分解行为,PG-d的玻璃化转变温度为98.9℃,800℃残碳率为22%。此外,通过基于愈创木酚的苯并嗪G-d与传统双酚A-苯胺型苯并[口恶]嗪(B-a)按照不同的比例共混形成二元共混体系。当G-d含量为10%时,G-d/B-a体系固化物的冲击强度是B-a均聚体系固化物的3倍以上,表明G-d中的柔性长链结构可有效改善共聚体系固化物的韧性。The benzoxazine(G-d)was synthesised by using guaiacol(renewable phenolic compound),1,10-diaminodecane and p-formaldehyde,and confirmed the structure and purity of the monomer by fourier transform infrared spectroscopy(FT-IR),gel permeation chromatography(GPC)and nuclear magnetic resonance spectroscopy(NMR).Data obtained from differential thermal scanning(DSC),thermal gravimetric analysis(TGA)shown that the curing initiation temperature of G-d was 225℃and the peak maximum at 246℃.The G-d polybenzoxazine was prepared by conventional thermal curing process,and its curing behaviour,dynamic mechanical properties and thermal decomposition behavior were studied,which indicated that the glass transition temperature of G-d was 98.9℃and the char yield of 22%at 800℃.Moreover,this guaiacol based benzoxazine was blended in varying proportions with conventional bisphenol A based benzoxazine(B-a)as G-d/B-a binary system.The impact strength of G-d/B-a after curing attained three times as B-a polybenzoxazine when the content of G-d was 10%,which indicated that the flexible long-chain in G-d improved toughness in co-curing resins.

关 键 词：苯并[口恶]嗪 愈创木酚 癸二胺 固化 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]