激光敏感型含能配合物类起爆药研究进展  

Review on Laser Sensitive Energetic Complex Primary Explosives

作　　者：张陆 王霆威 王晓军 周遵宁[1] 李志敏[1] 张同来[1] 张建国[1] ZHANG LU;WANG Ting-wei;WANG Xiao-jun;ZHOU Zun-ning;LI Zhi-min;ZHANG Tong-lai;ZHANG Jian-guo(State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing 100081,China)

机构地区：[1]北京理工大学爆炸科学与技术国家重点实验室,北京100081

出　　处：《含能材料》2022年第4期385-395,共11页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金资助(U1830134,22175025)。

摘　　要：激光起爆作为一种新兴的起爆技术,可以有效解决传统起爆方式中存在的如杂散电流干扰等安全问题。激光敏感起爆药作为激光起爆序列中的能量输出载体,是激光起爆系统的重要组成部分。目前配合物类激光敏感起爆药已成为研究热点之一。概述了以链状含氮化合物、三唑、四唑、四嗪类化合物为配体的含能配合物的合成和激光起爆性能方面的发展现状,分析了各类药剂的优点以及存在的问题,总结了部分激光起爆机理,并对未来新型激光起爆药研发进行了展望,指出开发新型富氮配体仍是激光敏感型含能配合物类起爆药未来研究的重要方向。As a new initiation technology,laser initiation can effectively solve the safety problems existing in traditional initiation methods,such as stray current interference.As the energy output carrier in laser initiation sequence,the laser⁃sensitive primary explosive is an important part of the laser initiation system.At present,complex laser⁃sensitive primary explosive has becomes a research hotspot.The synthesis of energetic complexes with chain nitrogenous compounds,triazole,tetrazole,and tetrazine as ligands and the development status of laser initiation properties were summarized.The advantages and existing problems of vari⁃ous agents were analyzed,some laser initiation mechanisms were summarized,and the development of new laser⁃sensitive pri⁃mary explosives in the future was prospected.It is pointed out that the development of new nitrogen⁃rich ligands is still an impor⁃tant direction for the future research of laser sensitive energetic complex primary explosives.

关 键 词：富氮含能配合物 激光感度 链状含氮化合物 三唑类含能配合物 四唑类含能配合物 四嗪类含能配合物 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O64[理学—物理化学]