一种新型镍基配合物对高氯酸铵的催化热分解研究  

Catalytic thermal decomposition of ammonium perchlorate with a new nickel based complex

作　　者：罗小凡 郭佳彦 冯海萌 高学智 麻晓霞[1] LUO Xiaofan;GUO Jiayan;FENG Haimeng;GAO Xuezhi;MA Xiaoxia(College of Chemistry and Chemical Engineering of Ningxia University,Yinchuan Ningxia 750021,China)

机构地区：[1]宁夏大学化学化工学院,宁夏银川750021

出　　处：《石油化工应用》2022年第3期105-107,共3页Petrochemical Industry Application

基　　金：宁夏大学大学生创新创业训练计划自治区级项目,项目编号:S202110749079。

摘　　要：以3-氨基-1,2,4-三唑-5-羧酸为配体,通过扩散法制备了一种新型镍基含能配合物[Ni(Hatzc)_(2)(H_(2)O)_(2)]·H_(2)O,并对其进行了红外、粉末衍射、热重和元素分析等表征,分析了其结构。配合物[Ni(Hatzc)_(2)(H_(2)O)_(2)]·H_(2)O对高氯酸铵的热分解表现出良好的催化活性,有应用于含能燃烧催化剂的潜质。A novel nickel-based energetic complex[Ni(Hatzc)_(2)(H_(2)O)_(2)]·H_(2)O was prepared by diffusion method with 3-amino-1,2,4-triazole-5-carboxylic acid as ligand.The structure of the complex was characterized by IR,powder diffraction,thermogravimetric analysis and elemental analysis.The complex[Ni(Hatzc)_(2)(H_(2)O)_(2)]·H_(2)O shows good catalytic activity for the thermal decomposition of ammonium perchlorate,which exhibits the potential of energetic combustion catalysts.

关 键 词：3-氨基-1 2 4-三唑-5-羧酸 配合物 高氯酸铵 热分解 

分 类 号：O656.2[理学—分析化学]