Recent advances in polyoxoniobate-catalyzed reactions  

作　　者：Zheng-Yi Liu Yu-Diao Lin Hao-Yu Hui-Na Chen Zheng-Wei Guo Xin-Xiong Li Shou-Tian Zheng 

机构地区：[1]State Key Laboratory of Photocatalysis on Energy and Environment,College of Chemistry,Fuzhou University,Fuzhou,350108,China [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Science,Fuzhou,350002,China

出　　处：《Tungsten》2022年第2期81-98,共18页钨科技（英文）

基　　金：financially supported by the National Natural Science Foundations of China (Grant Nos. 22171045, 21773029 and 21971039);the Natural Science Fund of Fujian Province (Grant No. 2017J01579);Projects from State Key Laboratory of Structural Chemistry of China

摘　　要：The search for polyoxometalate-based catalysts has long attracted interest.Being designable in structure,stable and effective,polyoxoniobate-based catalysts have an exciting prospect for industrial applications.This paper not only summarizes recent advances in classic polyoxoniobate-catalyzed reactions,including chemical warfare agents and organic dyes degradation,epoxidation reactions,photocatalytic hydrogen evolution and base-catalyzed reactions but also discusses some representative cases and the speculative mechanism related to structures.In addition,the current challenges and perspectives in the fabrication of more efficient and promising polyoxoniobate-based catalysts are also presented.

关 键 词：POLYOXONIOBATE CATALYSIS Degaradation of chemical warfare agents Epoxidation reaction Photocatalytic hydrogen evolution Base-catalyzed reaction 

分 类 号：TQ426[化学工程]