胺化活性红195/聚合物微球的制备及其在棉织物染色中的应用  

Preparation of amino-modified Reactive Red 195/polymer nanospheres and its application on dyeing of cotton fabrics

作　　者：王东伟[1,2] 房宽峻[1,3,4] 刘秀明[1] 张鑫卿 安芳芳[1] WANG Dongwei;FANG Kuanjun;LIU Xiuming;ZHANG Xinqing;AN Fangfang(School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China;School of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China;State Key Laboratory for Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao, Shandong 266071, China;Eco-Textiles Collaborative Innovation Center of Shandong Province and the Ministry of Education, Qingdao, Shandong 266071, China;School of Textile Science and Engineering, Xi′an Polytechnic University, Xi′an, Shaanxi 710048, China)

机构地区：[1]天津工业大学纺织科学与工程学院,天津300387 [2]中原工学院纺织学院,河南郑州450007 [3]青岛大学生物多糖纤维成形与生态纺织国家重点实验室,山东青岛266071 [4]山东省生态纺织省部共建协同创新中心,山东青岛266071 [5]西安工程大学纺织科学与工程学院,陕西西安710048

出　　处：《纺织学报》2022年第4期90-96,共7页Journal of Textile Research

基　　金：国家重点研发计划项目(2017YFB0309800,2016YFC0400503)。

摘　　要：针对活性染料水解导致染料利用率低和环境污染等问题,采用乙二胺改性活性红195/聚合物微球制备了胺化活性红195/聚合物微球。探究了初始体系pH值、乙二胺质量分数、改性温度和时间对胺化活性红195/聚合物微球粒径和Zeta电位的影响,并考察在最佳工艺条件下制备的胺化活性红195/聚合物微球染色阳离子化棉织物的K/S值和颜色参数。结果表明:在初始体系pH值为11,乙二胺质量分数为40%,改性温度为60℃和改性时间为120 min条件下,可制得粒径为96.5 nm,多分散指数为0.075,Zeta电位为-33.7 mV的胺化活性红195/聚合物微球;染色后阳离子化棉织物的K/S值可达9.3,是相同用量活性红195上染棉织物K/S值的3.1倍,且色彩鲜艳度提高,耐摩擦色牢度和耐皂洗色牢度均达到4级及以上。In view of the problems that hydrolysis of reactive dyes leads to low utilization and environmental pollution,nanospheres were prepared by using ethylenediamine modified Reactive Red 195/polymer.The influence of initial bath pH value,mass fraction of ethylenediamine,temperature and time on the size and Zeta potential of amino-modified Reactive Red 195/polymer nanospheres were discussed,and the K/S values and color parameters of the cationic cotton fabrics dyed with the amino-modified Reactive Red 195/polymer nanospheres under the optimal conditions were investigated.The results show that the amino-modified Reactive Red 195/polymer nanospheres with an average hydration diameter of 96.5 nm,polydispersity index of 0.075 and Zeta potential of-33.7 mV were fabricated after modified with ethylenediamine under the conditions of the initial pH value 11,the mass fraction of ethylenediamine 40%,60℃for 120 min.The K/S value of the cationic cotton fabric dyed with the amino-modified Reactive Red 195/polymer nanospheres reaches up to 9.3,which is 3.1 times higher than the K/S value of the cotton fabric dyed with same dosage of Reactive Red 195,with improvement of color saturation.The rubbing and washing color fastness of dyed cotton fabrics are both equal to or higher than grade 4.

关 键 词：活性染料 彩色聚合物微球 阳离子化改性 棉织物染色 

分 类 号：TS193.2[轻工技术与工程—纺织化学与染整工程]