Robust and conductive hydrogel based on mussel adhesive chemistry for remote monitoring of body signals  

作　　者：Weijun LI Hao LIU Yuanyuan MI Miaoran ZHANG Jinmiao SHI Ming ZHAO Melvin A.RAMOS Travis Shihao HU Jianxiong LI Meng XU Quan XU 

机构地区：[1]State Key Laboratory of Heavy Oil Processing.Beijing Key Laboratory of Biogas Upgrading Utilization,Harvard SEAS-C UPB Joint L aboratory on Petroleum Science,China University of Petroleum,Beijing 102249,China [2]Department of Mechanical Engineering.California State University,Los Angeles,CA 90032,USA [3]Department of Orthopedics General Hospital of Chinese People's Liberat ion Army,Beijing 100853,China

出　　处：《Friction》2022年第1期80-93,共14页摩擦（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(Nos.51875577 and 81972901);Tribology Science Fund of State Key Laboratory of Tribology(No.SKLTKF16A06);Chinese PLA General Hospital Training Program"The National Science Found for Distinguished Young Scholars"(No.2019-JQPY-004);The Science Foundation of China University of Petroleum-Beijing(Nos.2462019QNXZ02 and 2462018BJC004);T.S.H.acknowledges the support from the U.S.National Science Foundation PREM Program(NSF DMR-1523588).

摘　　要：There is a high demand for hydrogels with multifunctional performance(a combination of adhesive,mechanical,and electrical properties)in biological,tissue engineering,robotics,and smart device applications.However,a majority of existing hydrogels are relatively rigid and brittle,with limited stretchability;this hinders their application in the emerging field of flexible devices.In this study,cheap and abundant potato residues were used with polyacrylamide(PAM)to fabricate a multifunctional hydrogel,and chitosan was used for the design of a three-dimentional(3D)network-structured hydrogel.The as-prepared hydrogels exhibited excellent stretchability,with an extension exceeding 900%and a recovery degree of over 99%.Due to the combination of physical and chemical cross-linking properties and the introduction of dopamine,the designed hydrogel exhibits a remarkable self-healing ability(80%mechanical recovery in 2 h),high tensile strength(0.75 MPa),and ultra-stretchability(900%).The resultant products offer superior properties compared to those of previously reported tough and self-healing hydrogels for wound adhesion.Chitosan and potato residues were used as scaffold materials for the hydrogels with excellent mechanical properties.In addition,in vitro experiments show that these hydrogels feature excellent antibacterial properties,effectively hindering the reproduction of bacteria.Moreover,the ternary hydrogel can act as a strain sensor with high sensitivity and a gauge factor of 1.6.The proposed strategy is expected to serve as a reference for the development of green and recyclable conductive polymers to fabricate hydrogels.The proposed hydrogel can also act as a suitable strain sensor for bio-friendly devices such as smart wearable electronic devices and/or for health monitoring.

关 键 词：properties HYDROGEL CONDUCTIVE 

分 类 号：TQ427.26[化学工程] TN911.7[电子电信—通信与信息系统]