生物基聚呋喃类高分子的合成与应用研究进展  

Research Progress in the Synthesis and Application of Bio-based Furan Polymers

作　　者：方咏甘 杨崇岭[2] 林建云 罗时荷[1] 杨诗敏 汪朝阳[1] FANG Yong-gan;YANG Chong-ling;LIN Jian-yun;LUO Shi-he;YANG Shi-min;WANG Zhao-yang(Key Laboratory of Theoretical Chemistry of Environment,Ministry of Education,Guangzhou Key Laboratory of Ana-lytical Chemistry for Biomedicine,School of Chemistry,South China Normal University,Guangzhou 510006,China;Guangdong Industry Polytechnic,Guangzhou 510300,China)

机构地区：[1]华南师范大学化学学院教育部环境理论化学重点实验室广州市生物医药分析化学重点实验室,广州510006 [2]广东轻工职业技术学院,广州510300

出　　处：《高分子通报》2022年第5期38-54,共17页Polymer Bulletin

基　　金：广东省基础与应用基础研究基金(2021A1515012342);广州市科技计划(202002030362)。

摘　　要：随着经济的迅猛发展和石油资源的不断枯竭,人们越来越重视将可再生资源转化为有用的化合物或聚合物。生物基聚呋喃类高分子具有单体来源广泛和良好的生态效益,可用于制备外包装材料、导电材料、自修复材料等,在许多领域存在着巨大的潜在应用价值,因此,其合成研究备受关注。本文以不同的反应单体与合成方法为依据,全面地总结了近10年来(特别是近5年)几种常见的聚呋喃及其衍生物的合成方法与应用研究进展,主要包括缩聚合成、金属催化偶联反应合成、氧化偶联聚合、基于其它非呋喃环原料的聚合以及Diels-Alder反应合成,并从所得产物的机械性能和使用功能等角度对各方法进行了简要的评价。着眼未来,性能优化与功能拓展仍是聚呋喃类高分子设计与合成的重点发展方向。With the rapid economic development and the continuous depletion of petroleum resources,more and more attention has been paid to converse the renewable resources into useful polymers or compounds.Bio-based furan polymers,not only having rich reserves of monomers,but also creating excellent ecological benefits,can be applied in many fields such as green packaging materials,conductive materials,self-healing materials and so on.The great application potential makes their synthesis researches being concentrated.Thus,based on different monomers and synthetic methods,e.g.,polycondensation,metal-catalyzed coupling reaction,oxidative coupling polymerization,polymerization based on non-furan materials,and Diels-Alder reaction,the synthesis and application of polyfurans and their derivatives in the past decade(especially in the last 5 years)are summarized.In addition,a brief evaluation of each method is discussed in combination of the mechanical property and function of the products.In the future,performance optimization and function expansion are still the vital development directions for the design and synthesis of furan polymers.

关 键 词：生物基聚呋喃类高分子 合成方法 缩聚 金属催化偶联反应 氧化偶联聚合 DIELS-ALDER反应 应用 

分 类 号：TQ317[化学工程—高聚物工业]