Electrochemiluminescence of Bare Glassy Carbon with Benzoyl Peroxide as the Coreactant in N,N-Dimethylformamide  

作　　者：ShuiJian He Kenneth Chu Jonathan Michael Wong Liu-Qing Yang Jonathan Ralph Adsetts Rui-Zhong Zhang Yan-Hua Chen Zhi-Feng Ding 

机构地区：[1]College of Materials Science and Engineering,Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,Nanjing Forestry University,Nanjing 210037,China [2]Department of Chemistry,The University of Western Ontario,London,ON N6A 5B7,Canada [3]Tianjin Key Laboratory of Molecular Photoelectronic Sciences,Department of Chemistry,Tianjin University,Tianjin 300072,China

出　　处：《Journal of Analysis and Testing》2020年第4期257-263,共7页分析检测（英文）

基　　金：support from Natural Sciences and Engineering Research Council Canada(NSERC,DG RGPIN-2013-201697,DG RGPIN-2018-06556 and SPG STPGP-2016-493924);Canada Foundation of Innovation,Ontario Innovation Trust(CFI/OIT,9040);Premier’s Research Excellence Award(PREA,2003);Western University.

摘　　要：The electrochemiluminescence(ECL)properties of many carbon materials have been reported with glassy carbon(GC),Pt,Au or indium tin oxide(ITO)as the working electrode(WE).As one type of carbon materials,GC itself can generate ECL signal.Some research groups have already noticed the ECL signal from GC WE and reported the results of GC WE with respect to their luminophores.However,comprehensive analyses of ECL properties of GC WE are rare.Herein,the ECL properties of GC WE in organic electrolyte with benzoyl peroxide as the coreactant are reported.Our results are of great importance to distinguish the true ECL data of luminophores from that of GC.

关 键 词：Glassy carbon Electrochemiluminescence(ECL) Spooling ECL spectroscopy ECL intensity COREACTANT Benzoyl peroxide 

分 类 号：O657.1[理学—分析化学]