基于可再生脂肪酸的水性环氧酯树脂的制备及应用  

Preparation and Application of Waterborne Epoxy Ester Resins Based on Renewable Fatty Acid

作　　者：许飞 张汉青 胡中 庄振宇 刘睿 饶兴兴 刘汉功 祝宝英 吴雪艳 陈力 左慧明 胡东波 梁晟源 刘明 Xu Fei;Zhang Hanqing;Hu Zhong;Zhuang Zhenyu;Liu Rui;Rao Xingxing;Liu Hangong;Zhu Baoying;Wu Xueyan;Chen Li;Zuo Huiming;Hu Dongbo;Liang Shengyuan;Liu Ming(National Engineering Research Center for Coatings,CNOOC Changzhou Paint and Coatings Industry Research Institute Co.,Ltd.,Changzhou,Jiangsu 213016,China)

机构地区：[1]中海油常州涂料化工研究院有限公司,国家涂料工程技术研究中心,江苏常州213016

出　　处：《涂层与防护》2022年第3期29-33,共5页Coating and Protection

摘　　要：为开发应用于中轻度防腐领域的单组分水性防护涂料,本文采用可再生脂肪酸和环氧树脂作为原材料,通过酯化反应制备环氧酯中间体,再使用乙烯基单体对环氧酯中间体进行接枝改性,制备水性环氧酯树脂。分别通过傅里叶变换红外光谱、激光衍射粒度分析仪和凝胶渗透色谱对所制备水性聚合物进行结构表征。在此基础上,将所制备的水性环氧酯树脂作为成膜树脂,配合颜填料和涂料助剂,制备得到水性环氧酯涂料,并对涂层性能进行了测试。To develop one-component waterborne protective coatings for atmospheres or industrial areas with low level or moderate corrosive pollution,waterborne epoxy ester resins were prepared by graft polymerization of vinyl monomers onto epoxy ester intermediate which was synthesized by esterification of renewable fatty acid and epoxy resin.The structure of the prepared aqueous polymers was characterized by Fourier transform infrared spectroscopy,laser diffraction particle size analyzer and gel permeation chromatography,respectively.Thus waterborne epoxy ester coatings were produced using waterborne epoxy ester resins,pigments,fillers and additive,etc.Moreover,the properties of the coatings were investigated.

关 键 词：单组分 水性防护涂料 可再生 脂肪酸 环氧酯 

分 类 号：TQ630.7[化学工程—精细化工]