Status and challenges facing representative anode materials for rechargeable lithium batteries  

作　　者：Liqiang Zhang Chenxi Zhu Sicheng Yu Daohan Ge Haoshen Zhou 

机构地区：[1]Institute of Intelligent Flexible Mechatronics,School of Mechanical Engineering,Jiangsu University,Zhenjiang 212013,Jiangsu,China [2]Center of Energy Storage Materials&Technology,College of Engineering and Applied Sciences,Jiangsu Key Laboratory of Artificial Functional Materials,National Laboratory of Solid State Microstructures,and Collaborative Innovation Center of Advanced Microstructures,Nanjing University,Nanjing 210093,Jiangsu,China [3]Energy Technology Research Institute,National Institute of Advanced Industrial Science and Technology(AIST),Tsukuba 305-8568,Japan

出　　处：《Journal of Energy Chemistry》2022年第3期260-294,I0008,共36页能源化学（英文版）

基　　金：supported by grants from the Natural Science Foundation of Jiangsu Province(BK20180098);the Open Research Fund of National Laboratory of Solid State Microstructures of Nanjing University(M32045&M33042)。

摘　　要：Rechargeable lithium batteries have been widely regarded as a revolutionary technology to store renewable energy sources and extensively researched in the recent several decades.As an indispensable part of lithium batteries,the evolution of anode materials has significantly promoted the development of lithium batteries.However,since conventional lithium batteries with graphite anodes cannot meet the ever-increasing demands in different application scenarios(such as electric vehicles and large-scale power supplies)which require high energy/power density and long cycle life,various improvement strategies and alternative anode materials have been exploited for better electrochemical performance.In this review,we detailedly introduced the characteristics and challenges of four representative anode materials for rechargeable lithium batteries,including graphite,Li_(4)Ti_(5)O_(12),silicon,and lithium metal.And some of the latest advances are summarized,which mainly contain the modification strategies of anode materials and partially involve the optimization of electrode/electrolyte interface.Finally,we make the conclusive comments and perspectives,and draw a development timeline on the four anode materials.This review aims to offer a good primer for newcomers in the lithium battery field and benefit the structure and material design of anodes for advanced rechargeable lithium batteries in the future.

关 键 词：Lithium batteries Anode GRAPHITE Li_(4)Ti_(5)O_(12) SILICON Silicon composite anode Lithium metal 

分 类 号：TM912[电气工程—电力电子与电力传动] TB30[一般工业技术—材料科学与工程]