蒽、菲、咔唑的溶解度测定及分离精制研究  

Solubility Measurement and Refining Method Research of Anthracene,Phenanthrene and Carbazole

作　　者：李芊慧 鄂永胜[1] 林利叶 李秋子 李悦 邢洁 LI Qian-hui;E Yong-sheng;LIN Li-ye;LI Qiu-zi;LI Yue;XING Jie(School of Biological and Chemical Engineering,Liaoning Institute of Science and Technology,Benxi 117004,China)

机构地区：[1]辽宁科技学院生物医药与化学工程学院,本溪117004

出　　处：《当代化工》2021年第12期2873-2876,共4页Contemporary Chemical Industry

基　　金：辽宁省自然科学基金项目,含芴基Cardo环结构新型聚碳酸酯的合成及性能研究(项目编号:20180550114);辽宁科技学院大学生创新创业训练计划项目,蒽、咔唑的液固相平衡研究及粗蒽的分离精制工艺设计(项目编号:202111430054)。

摘　　要：采用平衡法测定了蒽、菲、咔唑在溶剂甲苯、二甲苯、氯苯、吡啶、N-甲基吡咯烷酮和N,N-二甲基甲酰胺(DMF)中的溶解度。根据溶解度数据,选用二甲苯和DMF两种溶剂设计出粗蒽中蒽、菲、咔唑的分离精制方法。通过测定40℃下蒽、菲、咔唑在不同含水量的DMF中的溶解度数据,用含水10%的DMF代替无水DMF,提高了产品精蒽和精咔唑的收率。The equilibrium method was used to measure the solubilities of anthracene,phenanthrene,and carbazole in the solvents toluene,xylene,chlorobenzene,pyridine,N-methylpyrrolidone and N,N-dimethylformamide(DMF).According to the solubility data,the separation and purification method of anthracene,phenanthrene and carbazole in crude anthracene was designed by using two solvents:xylene and DMF.By measuring the solubility of anthracene,phenanthrene,and carbazole in DMF with different water mass fraction at 40 ℃,the yield of anthracene and carbazole was improved by replacing anhydrous DMF with DMF containing 10% water.

关 键 词：蒽 菲 咔唑 溶解度 

分 类 号：TQ420.6[化学工程]