核取代萘二酰亚胺衍生物超分子自组装体系的研究进展  

Supramolecular Self-assembly of Core-Substituted Naphthalenediimides

作　　者：仇中选 张娟[2] 辛飞飞 QIU Zhong-xuan;ZHANG Juan;XIN Fei-fei(School of Biological and Chemical Engineering,Qingdao Technical College,Qingdao 266555,China;Unconventional Petroleum Research Institute,China University of Petroleum,Beijing 102249,China;College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,China)

机构地区：[1]青岛职业技术学院生物与化工学院,山东青岛266555 [2]中国石油大学(北京)非常规油气科学技术研究院,北京102249 [3]青岛科技大学化学与分子工程学院,山东青岛266042

出　　处：《化学试剂》2022年第5期643-652,共10页Chemical Reagents

基　　金：碳氟/碳氢混合表面活性剂自组装囊泡凝胶的可控构筑及其流变性质研究项目(21503274)。

摘　　要：超分子自组装是体系中各结构单元之间的一种自发的组织行为,能够形成纳米级或者微米级的微结构,可用于制备具有特定性质以及功能化的材料。核取代萘二酰亚胺衍生物(cNDIs)因其独特的结构特点与光电性能,是超分子自组装体系中一类重要的构筑基元,在超分子化学领域以及材料科学领域等表现出极大的应用价值。如何提高cNDIs超分子组装体的结构与性能调控效率,拓展其功能,促进其实际应用是现阶段的主要研究热点。综述国内外cNDIs自组装体系的文献报道,总结并阐述了调控cNDIs分子自组装行为的3种主要方式:设计cNDIs分子结构,改变体系环境,使用模板。最后,对该类超分子体系的研究方向与发展趋势进行了简要展望。Supramolecular self-assembly rests on the spontaneous organization of components and forms various micro-or nanostructures to prepare functional materials with unique properties.Core-substituted naphthalenediimides(cNDIs)which possess unique molecular structures and opto-electrical properties are widely employed in supramolecular chemistry.Now,the main researches on cNDIs-based supramolecular assemblies include:increasing the modulation efficiency of microstructures and properties;extending the functionalities and promoting the applications.The recent progress in supramolecular self-assemblies based on cNDIs was reviewed.Three main modulating patterns of self-assemblies,including the design of cNDIs molecular structures,changing external environment and templated self-assembly were summarized.Finally,the development potential of this field was briefly discussed.

关 键 词：核取代萘二酰亚胺 超分子化学 可调控 自组装 微观结构 

分 类 号：O641.3[理学—物理化学]